Ei-ichi Negishi

Ei-ichi Negishi is a Japanese chemist who is a co-recipient of 2010 Nobel Prize for chemistry in Sweden for his discovery of the Negishi Coupling.

Ei-ichi Negishi became a postdoctoral associate at Purdue University and was appointed as assistant to Professor H. C. Brown’s in 1968. During his postdoc years he began investigating various C—C bond forming reactions of organoboranes. In 2000 he was awarded the Royal Society of Chemistry’s Sir Edward Frankland Prize Lectureship.

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  • American Academy of Arts & Sciences, 2011
  • Order of the Griffin, Purdue University, 2011
  • Sagamore of the Wabash, State of Indiana, 2011
  • Japanese Order of Culture, 2010
  • Japanese Person of Cultural Merit, 2010
  • Nobel Prize in Chemistry, 2010
  • American Chemical Society Award for Creative Work in Synthetic Organic Chemistry, 2010
  • Yamada-Kaga Prize, 2007
  • Gold Medal of Charles University, Prague, Czech Republic, 2007
  • Sigma Xi Award – Purdue Univeristy, 2003
  • Citation of Negishi Cross-Coupling – Merck Index, 13th Ed., 2001
  • Sir Edward Frankland Prize Lectureship, 2000
  • Herbert C. Brown Distinguished Professor – Purdue University, 1999
  • Alexander von Humboldt Award, Senior Researcher Germany, 1998-2001
  • Herbert N. McCoy Award – Purdue University, 1998
  • American Chemical Society Organometallic Chemistry Award, 1998
  • Chemical Society of Japan Award, 1996
  • A. R. Day Award, 1996
  • J. S. Guggenheim Memorial Foundation Fellowship, 1987
  • Fulbright-Smith-Mund All Expense Scholarship, 1960-63
  1. Basic Cleavages of Arylsulfonamides. Negishi, E.; Day, A. R. J. Org. Chem. 1965, 30, 43-48.
  2. The Carbonylation of Thexyldialkylboranes. A New General Synthesis of Ketones. Brown, H. C.; Negishi, E. J. Amer. Chem. Soc. 1967, 89, 5285-5287.
  3. Carbonylation of the Organoboranes from the Cyclic Hydroboration of Dienes with Thexylborane. A Simple Procedure the Conversion of Dienes into Cyclic Ketones. Brown, H. C.; Negishi, E. J. Amer. Chem. Soc., 1967, 89, 5477-5478.
  4. Carbonylation of Perhydro-9b-boraphenalene to Form Perhydro-9b-phenalenol. A New General Synthesis of Polycyclic Derivatives. Brown, H. C.; Negishi, E. J. Amer. Chem. Soc., 1967, 89, 5478-5480.
  5. A General Stereospecific Annelation for the Synthesis of trans-Fused Polycyclic Ketone via Hydroboration- Carbonylation Brown, H. C.; Negishi, E. Chem. Commun., 1968, 594-595.
  6. Conversion of Linear Trienes into Bicyclic Boranes via Hydroboration-Isomerization and Their Carbonylation. A Simple Synthesis of Angularly Substituted Bicyclic Alcohols Brown, H. C.; Negishi, E. J. Amer. Chem. Soc. 1969, 91, 1224-1226.
  7. Reaction of Cyclic Organoboranes from Dienes with Methyl Vinyl Ketone. A Convenient of ?-Hydroxy-ketones from Dienes via Hydroboration Suzuki, A.; Nozawa S.; Itoh, M.; Brown, H. C.; Negishi, E.; Gupta, S. K. Chem. Commun. 1969, 1009-1010.
  8. Organoboranes. IX. Structure of the Organoboranes Formed in the Reaction of 1,3-Butadiene and Diborane in the Stoichiometric Ratio. An Unusual Thermal Isomerization of the Organoboranes Brown, H. C.; Negishi, E.; Gupta, S. K. J. Amer. Chem. Soc. 1970, 92, 2460-2467.
  9. The Reaction of B-Methoxydialkylboranes with Lithium Aluminum Hydride in the Presence of Olefins. A New and General Synthesis of Acyclic and Cyclic Mixed Trialkylboranes and Their Conversion into the Corresponding Trialkylcarbinols via Carbonylation-Oxidation Brown, H. C.; Negishi, E.; Gupta, S. K. J. Amer. Chem. Soc. 1970, 92, 6648-6649.

10.  A Facile Opening of the Borolane Ring with Borane. A Simple Entry into 12-Tetramethylenediboranes Brown, H. C.; Negishi, E.; Burke, P. L. J. Amer. Chem. Soc. 1970, 92, 6649-6651.

11.  A Simple Synthesis of Bisborinane and Its Applicability in Hydroboration for the Preparation of B-Alkylborinanes Brown, H. C.; Negishi, E. J. Organometal. Chem. 1971, 26, C67-C69.

12.  A Simple Synthesis of Bis(3,5-dimethyl)borinane and Bis(3,6-dimethyl)borepane as New Valuable Reagents via Cyclic Hydroboration Brown, H. C.; Negishi, E. J. Organometal. Chem. 1971, 28, C1-C4.

13.  A New Four-Carbon-Atom Homologation Involving the Free Radical Chain Reaction of 1,3-Butadiene Monoxide with Organoboranes. Synthesis of 4-Alkyl-2-buten-1-ols from Olefins via Hydroboration Suzuki, A.; Miyaura, N.; Itoh, M.; Brown, H. C.; Holland, G. W.; Negishi, E. J. Amer. Chem. Soc. 1971, 93, 2792-2793.

14.  Organoboranes, XII. Hydroboration of 1,3-Butadiene with Borane in Tetrahydrofuran in a Ratio Equal to or Smaller than 1:1. Interconversion Between B-Alkylborolane and 1,2-Tetramethylenediboranes. Brown, H. C.; Negishi, E.; Burke, P. L. J. Amer. Chem. Soc. 1971, 93, 3400-3409.

15.  The Facile Reaction of B-Alkylboracyclanes with a,ß-Unsaturated Carbonyl Derivatives. A Convenient Procedure for the Transfer of Secondary and Tertiary Alkyl Groups from Boron to Carbon in the 1,4-Addition Reaction Brown, H. C.; Negishi, E. J. Amer. Chem. Soc. 1971, 93, 3777-3779.

16.  Bisborolane. A Highly Elusive Bisboracyclane Brown, H. C.; Negishi, E. J. Amer. Chem. Soc. 1971, 93, 6682-6683.

17.  The Cyclic Hydroboration of Dienes. A Simple Convenient Route to Heterocyclic Organoboranes Brown, H. C.; Negishi, E. Pure Appl. Chem. 1972, 29, 527-545.

18.  A General Multi-Carbon Homologation of Olefins via Hydroboration-Carbonylation Negishi, E.; Brown, H. C. Synthesis 1972, 196-197.

19.  The Reaction of Organoboranes Containing a Tertiary Alkyl Group with Carbon Monoxide. A New Approach to the Synthesis of Highly Branched Trialkylcarbinols Negishi, E.; Brown, H. C. Synthesis 1972, 197-199.

20.  Hydroboration. XXXI. The Cyclic Hydroboration of Dienes with Borane in Tetrahydrofuran in the Molar Ratio of 1:1. Brown, H. C.; Negishi, E.; Burke, P. L. J. Amer. Chem. Soc. 1972, 94, 3561-3567.

21.  Hydroboration. XXXII. The Cyclic Hydroboration of Dienes with Thexylboranes Brown, H. C.; Negishi, E. J. Amer. Chem. Soc. 1972, 94, 3567-3572.

22.  Monomeric Dialkylboranes Negishi, E.; Katz, J-J.; Brown, H. C. J. Amer. Chem. Soc. 1972, 94, 4025-4027.

23.  Remarkably Facile and Selective Dehydroboration of Tetramethylethylene from Thexylmonoalkylboranes under the Influence of Triethylamine. A Novel, Convenient Synthesis of Monoalkylboranes in Trielethylaminates. Brown, H. C.; Negishi, E.; Katz, J-J. J. Amer. Chem. Soc. 1972, 94, 5893-5894.

24.  Hydroboration. XXXIII. The Cyclic Hydroboration of 1,4-Pentadiene with Borane in Tetrahydrofuran. Thermal Behavior of the Organoborane Derivatives and a Simple Synthesis of Bisborinane and B-Alkylborinanes Negishi, E; Burke, P. L.; Brown, H. C. J. Amer. Chem. Soc. 1972, 94, 7431-7437.

25.  Applications of Thexylkylboranes to Stereoselective Synthesis of trans Disubstituted Olefins Negishi, E.; Katz, J-J.; Brown, H. C. Synthesis, 1972, 555-556.

26.  Hydroboration. XXXIV. The Cyclic Hydroboration of 1,5-Hexadiene with Borane in Tetrahydrofuran and 9-Borabicycl (3.3.1)nonane. A New Convenient Route to the Borepane Ring System Utilizing 9-Borabicyclo(3.3.1)nonane Burke, P. L.; Negishi, E.; Brown, H. C. J. Amer. Chem. Soc. 1973, 95, 3654-3662.

27.  A Highly Stereoselective and General Synthesis of Conjugated trans, trans-Dienes and trans-Alkenyl Ketones via Hydroboration. Negishi, E.; Yoshida, T. Chem. Commun. 1973, 606-607.

28.  Hydroboration. XXXV. The Cyclic Hydroboration of 2,4-Dimethyl-1,4-pentadiene and 2,5-Dimethyl-1,5-hexadiene. A Simple Synthesis of Bis(3,5-dimethyl)borinane and Bis(3,6-dimethyl)borepane and Their Application to the 1,4- Addition Reaction of Organoboranes Negishi, E.; Brown, H. C. J. Amer. Chem. Soc. 1973, 95, 6757-6763.

29.  An Intramolecular Michael Reaction Involving Borate Complexes. A Novel Synthesis of ß-Hydroxycarboxyic Acids Negishi, E.; Yoshida, T. J. Amer. Chem. Soc. 1973, 95, 6837-6838.

30.  Stereoselective Synthesis of Conjugated trans-Enynes Readily Convertible into Conjugated cis, trans-Dienes and its Application to the Synthesis of the Pheromone Bombykol Negishi, E.; Lew, G.; Yoshida, T. Chem. Commun. 1973, 874-875.

31.  Carbonylation of Organoboranes Negishi, E. Intra-Science Chem. Reports 1973, 7, 81-94.

32.  Thexylborane-A Highly Versatile Reagent in Organic Synthesis via Hydroboration Negishi, E.; Brown, H. C. Synthesis 1974, 77-89.

33.  A Stereoselective Synthesis of Partially Substituted 1,2,3-Butatriene Derivatives via Hydroboration Yosida, T.; Williams, R. M.; Negishi, E. J. Amer. Chem. Soc. 1974, 96, 3688-3690.

34.  A Novel Stereoselective Synthesis of (E) and (Z)-a,ß-Unsaturated Carboxylic Esters via Hydroboration Negishi, E.; Lew, G.; Yoshida, T. J. Org. Chem. 1974, 96, 2321-2322.

35.  A Novel Copper-Containing Hydride Species and its Application to the Reduction of Organic Compounds Yoshida, T.; Negishi, E. Chem. Commun. 1974, 762-763.

36.  Novel and Regioselective Aromatic Double Substitution Involving Borate Anions and a Regio- and Stereoselective Route to Dihydroaromatic Derivatives Negishi, E.; Merrill, R. E. Chem. Commun. 1974, 860-861.

37.  Tetrahydrofuran-Promoted Aryl-Alkyl Coupling Involving Organolithium Reagents Merrill, R. E.; Negishi, E. J. Org. Chem. 1974, 39, 3452-3453.

38.  A Novel Regio- and Chemoselective Aryl Ketone Synthesis by the Reaction of Arylborate Anions with Aryl Chlorides Negishi, E.; Abramovitch, A.; Merrill, R. E. Chem. Commun. 1975, 138-139.

39.  A General One-Carbon Homologation of Organoboranes via a-Thioorganoborate Anions Negishi, E.; Yoshida, T.; Silveira, A. Jr.; Chiou, B. L. J. Org. Chem. 1975, 814-816.

40.  Organoboranes and Organoborate Anions – New Classes of Electrophiles and Nucleophiles in Organic Synthesis. Negishi, E. J. Chem. Educ. 1975, 52, 159-165.

41.  Hydroboration. XXXVII. The Structural Study of the Hydroboration of Olefins with Thexylborane. A Simple Synthesis of Thexylmonoalkylboranes Brown, H. C.; Negishi, E.; Katz, J. J. J. Amer. Chem. Soc. 1975, 97, 2791-2798.

42.  Hydroboration. XXXVIII. The Structural Study of the Hydroboration of Olefins with Thexylmonoalkylboranes. A Convenient Route to Thexyldialkylboranes, ”Mixed” Dialkyl-boranes and ”Mixed” Trialkylboranes Brown, H. C.; Katz, J. J.; Lanes, C. F.; Negishi, E. J. Amer. Chem. Soc. 1975, 97, 2799-2804.

43.  An Intermolecular Alkyl-Transfer Reaction of Tetraalkylborate Anions with Acyl Halides. A Novel Method for Moderating the Carbanion Reactivity Negishi, E.; Yoshida, T.; Chiu, K. W. J. Org. Chem. 1975, 40, 1676-1677.

44.  A Steroselctive Synthesis of cis-Alkenylboranes Negishi, E.; Williams, R. M.; Lew, G.; Yoshida, T. J. Organometal. Chem., 1975, 92, C4-C6.

45.  A Convenient Method for the Tertiary Alkyl-Alkynyl Coupling via Organoalanes Negishi, E.; Baba, S. J. Amer. Chem. Soc., 1975, 97, 7385-7387.

46.  Stereoselective Synthesis of ß-Hydroxy Substituted trans-Alkenes by the Reaction of trans-Alkenyltrialkylaluminates with Epoxides Negishi, E.; Baba, S.; King, A. O. J. Chem. Soc. Chem. Commun. 1976, 17-18.

47.  Preparation of Secondary Alcohols by Reaction of Trialkylboranes with Bis(phenylthio)-methyllithium Hughes, R. J.; Pelter, A.; Smith, K.; Negishi, E.; Yoshida, T. Tetrahedron Lett. 1976, 87-88.

48.  Chemistry of Organoborates Negishi, E. J. Organometal. Chem., 1976, 108, 281-324.

49.  An Efficient Synthesis of Juvabione and Todomatuic Acid via Hydroboration-Carbonylation Negishi, E.; Sabanski, M.; Katz, J. J.; Brown, H. C. Tetrahedron 1976, 32, 925-926.

50.  An Unusually Facile Dehydroboration of Triorganoboranes Formed by Treatment of Alkenyltrialkylborates with Hydrochloric Acid Chiu, K. W., Negishi, E.; Plante, M. S.; Silveira, A. Jr. Organometal. Chem. 1976, 112, C3-C6.

51.  A Stereoselective Synthesis of Disubstituted trans-Alkenes by the Reaction of trans-Alkenyltrialkylaluminates with Alkyl Halides and Sulfonates Baba, S.; Van Horn, D. E.; Negishi, E. Tetrahedron Lett. 1976, 1927-1930.

52.  A Novel Intermolecular Transfer Reaction ofAlkenyltrialkylborates with Aqueous Bases and its Application to the Protonolysis of Alkenylboron Derivatives. Negishi, E.; Chiu, K. W. J. Org. Chem. 1976, 41, 3484-3486.

53.  Organoboron and Organoaluminum Compounds as Unique Nucleophiles in Organic Synthesis Negishi, E. ”New Applications of Organometallics Reagents in Organic Synthesis,” Seyferth, D., Ed., Elsevier, Amsterdam, 1976, 93-125.

54.  Novel Stereoselective Alkenyl-Aryl Coupling via Nickel-Catalyzed Reaction of Alkenylalanes with Aryl Halides Negishi, E.; Baba, S. J. Chem. Soc. Chem. Comm. 1976, 596-597.

55.  A Novel Stereospecific Alkenyl-Alkenyl Cross-Coupling of a Palladium- orNickel-Catalyzed Reaction of Alkenylalanes with Alkenyl Halides Baba, S.; Negishi, E. J. Amer. Chem. Soc. 1976, 98, 6729-6731.

56.  Organoborane Heterocycles via Cyclic Hydroboration of Dienes Negishi, E.; Kulkarni, S. U.; Brown, H. C. Heterocycles 1976, 5, 883-904.

57.  A Highly Efficient Chemo-, Regio-, and Stereoselective Synthesis of (7E,9E)-Dodecadien-1-yl Acetate. A Sex Pheromone of Lobesia botrana, via A Functionalized Organoborate. Negishi, E.; Abramovitch, A. Tetrahedron Lett. 1977, 411-414.

58.  Novel Borate Anion-Assisted Cyclization. Facile Rearrangement of 1-Cyclopropylidene-alkylboranes to Homopropargylboranes Merrill, R. E.; Allen, J. L.; Abramovitch, A.; Negishi, E. Tetrahedron Lett. 1977, 1019-1022.

59.  Selective Carbon-Carbon Bond Formation via Transition Metal Catalysis. 3. A Highly Selective Synthesis of Unsymmetrical Biaryls and Diarylmethanes by the Nickel- or Palladium-Catalyzed Reaction of Aryl- and Benzylzinc Derivatives with Aryl Halides Negishi, E.; King, A. O.; Okudado, N. J. Org. Chem. 1977, 42, 1821-1823.

60.  Selective Carbon-Carbon Bond Formation via Transition Metal Catalysis. 4. A Novel Approach to Cross-Coupling Exemplified by the Ni-Catalyzed Reaction of Alkenylzirconium Derivatives with Aryl Halides Negishi, E.; Van Horn, D. E. J. Am. Chem. Soc. 1977, 99, 3168-3170.

61.  A Novel Synthesis of an ?-Alkynylorganometallic Reagent via Triple Bond Isomerizationwith with Potassium 3- Aminopropylamide: ?-Alkynylorganometallic Reagent via Riple Bond Isomerization with Potassium 3-Aminopropylamide: ?-(9-Borabicycl(3.3.1) nonyl)-1-Alkynes Brown, C. A.; Negishi, E. J. Chem. Soc. Chem. Comm. 1977, 318-319.

62.  Synthesis of Secondary or Tertiary Alcohols by Reactions of Trialkylboranes with Acyl Carbanion Equivalents Hughes, R. J.; Ncube, S.; Pelter, A.; Smith, K.; Negishi, E.; Yoshida, T. J. Chem. Soc., Perkin I, 1977, 1172-1176.

63.  Boraheterocycles via Cyclic Hydroboration Brown, H. C.; Negishi, E. Tetrahedron 1977, 33, 2331-2357.

64.  Highly General Stereo-, Regio- and Chemoselective Synthesis of Terminal and Internal Conjugated Enynes by the Pd-Catalyzed Reactions of Alkynylzinc Reagents with Alkenyl Halides King, A. O.; Okukado, N.; Negishi, E. J. Chem. Soc. Chem. Commun. 1977, 683-684.

65.  A General Synthesis of Terminal and Internal Arylalkynes by the Pd-Catalyzed Reaction of Alkynylzinc Reagents with Aryl Halides King, A. O; Negishi, E.; Villani, F. J., Jr.; Silveira, A., Jr. J. Org. Chem. 1978, 43, 358-360.

66.  A Highly Stereo-, Regio-, and Chemoselective Synthesis of Conjugated Dienes by the Palladium-Catalyzed Reaction of (E)-1-Alkenylzirconium Derivatives with Alkenyl Halides Okukado, N.; Van Horn, D. E.; Klima, W. L.; Negishi, E. Tetrahedron Lett. 1978, 1027-1030.

67.  Controlled Carbometallation. The Reaction of Acetylenes with Organoalane-Zirconocene Dichlorides Complexes as a Route to Stereo- and Regio-Defined Trisubstituted Olefins Van Horn, D. E.; Negishi, E. J. Am. Chem. Soc. 1978, 100, 2252-2254.

68.  Double and Multiple Catalysis in the Cross-Coupling Reaction and Its Application to the Stereo- and Regioselective Synthesis of Trisubstituted Olefins Negishi, E.; Okukado, N.; King, A. O.; Van Horn, D. E.; Spiegel, B. I. J. Am. Chem. Soc. 1978, 100, 2254-2256.

69.  Controlled Carbometallation. II. The Addition Reaction of Trimethylalane-Titanocene Dichloride with Acetylenes Van Horn, D. E.; Valente, L. F.; Idacavage, M. J.; Negishi, E. J. Organometal. Chem. 1978, 156, C20-C24.

70.  One-Step Conversion of Terminal Acetylenes into Terminally Functionalized. (E)-3-Methyl-2-alkenes via Zirconium- Catalyzed Carboalumination. A Simple and Selective route to Terpenoids Okukado, N.; Negishi, E. Tetrahedron Lett. 1978, 2357-2360.

71.  Scope of the Reaction of Organoborates with Organolithiums as a Method of Preparation of Lithium Organoborates. Stability of Lithium Organoborates Negishi, E.; Idacavage, M. J.; Chiu, K. W.; Yoshida, T.; Abramovitch, A.; Goettel, M. E.; Silveira, A., Jr.; Bretherick, H. D. J. Chem. Soc., Perkin II. 1978, 1225-1232.

72.  Selective Carbon-Carbon Bond Formation via Transition Metal Catalysis: Is Nickel or Palladium Better than Copper? Negishi, E. ”Aspects of Mechanism and Organometallic Chemistry,” Brewster, J. H., ed., Plenum Press, New York, 1978, 285-317.

73.  A Highly Selective Method for a-Alkylation of Ketones via Potassium Enoxytrialkylborates Negishi, E.; Idacavage, M. J.; Dipasquale, F.; Silveira, A., Jr. Tetrahedron Lett. 1979, 845-848.

74.  A Selective Synthesis of (E)-ß-Methylalkenyl Iodides via Zirconium-Catalyzed Carboalumination of Terminal Acetylenes. Negishi, E.; Van Horn, D. E.; King, A. O.; and Okukado, N. Synthesis, 1979, 501-502.

75.  NMR Determination of n-Butyllithium. Silveira, A., Jr.; Bretherick, H. D., Jr.; Negishi, E. J. Chem. Educ. 1979, 56, 560.

76.  Palladium-Catalyzed Acetylene Syntheses Negishi, E. Preprints Petroleum Div. ACS, 1979, 24, 226-232.

77.  Perhydro-9b-boraphenalene and Perhydro-9b-phenalenol Negishi, E.; Brown, H. C. Org. Synth., 1983, 61, 103-111.

78.  ”Organometallics in Organic Synthesis,” Vol. 1, General Discussions and Organometallics of Main Group Metals in Organic Synthesis Negishi, E. Wiley-Interscience, 1980, 532 pp.

79.  Remarkable Countercation Effect in the Reaction of Organoborates with Enolates Idacavage, M. J.; Negishi, E.; Brown, C. A. J. Organometal. Chem. 1980, 185, C55-C57.

80.  Conversion of Methyl Ketones into Terminal Acetylenes and (E)-Trisubstituted Olefins of Terpenoid Origin. Negishi, E.; King, A. O.; Klima, W. L.; Patterson, W.; Silveira, A., Jr. J. Org. Chem. 1980, 45, 2526-2528.

81.  Palladium-Catalyzed Cross-Coupling Reaction of Homoallylic or Homopropargylic Organozincs with Alkenyl Halides as a New Selective Route to 1,5-Dienes and 1,5-Enynes Negishi, E.; Valente, L. F.; Kobayashi, M. J. Am. Chem. Soc. 1980, 102, 3298-3299.

82.  A Novel Zirconium-Catalzyed Hydroalumination of Olefins Negishi, E.; Yoshida, T. Tetrahedron Lett. 1980, 1501-1504.

83.  A Selective and Efficient Synthesis of (E)-4-Methyl-3-alken-1-ols via Zirconium Catalyzed Carboalumination of Terminal Alkynes Kobayashi, M.; Valente, L. F.; Negishi, E.; Patterson, W.; Silveira, A., Jr. Synthesis 1980, 1034-1035.

84.  A Pd-Catalyzed Stereospecific Substitution Reaction of Homoallylzincs with ß-Bromo-Substituted a,ß-Unsaturated Carbonyl Derivatives as a Novel Route to Butenoilides and Related Natural Products of Terpenoid Origin. A Highly Selective Synthesis of Mokupalide Kobayashi, M.; Negishi, E. J. Org. Chem. 1980, 45, 5223-5225.

85.  1,1-Dimetalloalkenes Containing Aluminum as Well as Titanium or Zirconium. Their Structures and Use as Novel Alkenylidene and Alkenyl Transfer Agents Yoshida, T.; Negishi, E. J. Am. Chem. Soc. 1981, 103, 1276-1277.

86.  Palladium-Catalyzed Stereo- and Regiospecific Coupling of Allylic Derivatives with Alkenyl and Arylmetals. A Highly Selective Synthesis of 1,4-Dienes Matsushita, H.; Negishi, E. J. Am. Chem. Soc., 1981, 103, 2882-2884.

87.  A Versatile and Selective Route to Difunctional Trisubstituted (E)-Alkene Synthons via Zirconium-Catalyzed Carboalumination of Alkynes Rand, C. L.; Van Horn, D. E.; Moore, M. W.; Negishi, E. J. Org. Chem. 1981, 46, 4093-4096.

88.  Highly Selected Synthesis of Allylated Arenes and Diarylmethanes via Palladium-Catalyzed Cross Coupling Involving Benzylic Derivatives Negishi, E.; Matsushita, H.; Okukado, N. Tetrahedron Lett. 1981, 22, 2715-2718.

89.  Mechanism of the Zr-Catalyzed Carboalumination of Alkynes. Evidence for Direct Carboalumination Negishi, E.; Yoshida, T. J. Am. Chem. Soc. 1981, 103, 4985-4987.

90.  Scope of the Palladium-Catalyzed Coupling Reaction of Organometallics with Allylic Electrophiles. Effect of the Leaving Group Negishi, E.; Chatterjee, S.; Matsushita, H. Tetrahedron Lett. 1981, 22, 3737-3740.

91.  Bimetallic Catalytic Systems Containing Ti, Zr, Ni, and Pd. Their Applications to Selective Organic Syntheses Negishi, E. Pure Appl. Chem. 1981, 53, 2333-2356.

92.  Highly Sensitive and Convenient Method for the Synthesis of 1,5-Enynes and 1,5-Dienes by the Reaction of 1,3-Dilithiopropargyl Phenyl Sulfide with Allylic Halides Negishi, E.; Rand, C. L.; Jadhav, K. P. J. Org. Chem. 1981, 46, 5041-5044.

93.  Anti Stereospecificity in the Palladium-Catalyzed Reactions of Alkenyl-metal or Aryl-metal Derivatives with Allylic Electrophiles. Matsushita, H.; Negishi, E. J. Chem. Soc. Chem. Commun. 1982, 160-161.

94.  Stereo- and Regioselective Routes to Allylic Silanes Negishi, E.; Luo, F.-T.; Rand, C. L. Tetrahedron Lett. 1982, 23, 27-30.

95.  A Regiospecific Synthesis of Carbosubstituted Heteroaromatic Derivatives via Pd-Catalyzed Cross Coupling Negishi, E.; Luo, F.-T.; Frisbee, R.; Matsushita, H. Heterocycles, 1982, 18, 117-122.

96.  A Selective Synthesis of Alkenylmercuric Chlorides via Alkenylalanes Negishi, E.; Jadhav, K. P.; Daotien, N. Tetrahedron Lett. 1982, 23, 2085-2086.

97.  Selective and Convenient Synthesis of ß,ß-Disubstituted Alkenylboranes and Alkenylzirconiums via Carboalumination of Alkynes Negishi, E.; Boardman, L. D. Tetrahedron Lett. 1982, 23, 3327-3330.

98.  A Highly Regio- and Stereospecific Palladium-Catalyzed Allylation of Enolates Derived from Ketones Negishi, E.; Matsushita, H.; Chatterjee, S.; John, R. A. J. Org. Chem. 1982, 47, 3188-3190.

99.  Bimetallic Reagent Systems Containing a Main Group Metal and a Transition Metal (in Japanese) Negishi, E. Kagaku Zokan (in Japanese) No. 96, 49-61 Nozaki, H.; Mukaiyama, T.; Yamamoto, H. eds. Kagaku Dojin, Kyoto, 1982.

  1. Palladium- or Nickel-Catalyzed Cross Coupling. A New Selective Method for Carbon-Carbon Bond Formation Negishi, E. Acc. Chem. Res. 1982, 15, 340-348.
  2. General Discussions of the Organoboron Reactions Negishi, E. ”Comprehensive Organometallic Chemistry”, Wilkinson, G. T.; Stone, F. G. A.; Abel, E. W., Eds. Pergamon, Chap. 45.6, pp. 279-288, 1982.
  3. Aliphatic Organoboron Compounds Negishi, E. ”Comprehensive Organometallic Chemistry”, Wilkinson, G. T.; Stone, F. G. A.; Abel, E. W., Eds. Pergamon, Chap. 45.7, pp. 289-329, 1982.
  4. Alkenylboron Compounds Negishi, E. ”Comprehensive Organometallic Chemistry”, Wilkinson, G. T.; Stone, F. G. A.; Abel, E. W., Eds. Pergamon, Chap. 45.8, pp. 331-352, 1982.
  5. Arylboron Compounds Negishi, E. ”Comprehensive Organometallic Chemistry”, Wilkinson, G. T.; Stone, F. G. A.; Abel, E. W., Eds. Pergamon, Chap. 45.9, pp. 353-368, 1982.
  6. Alkynylboron Compounds Negishi, E. ”Comprehensive Organometallic Chemistry”, Wilkinson, G. T.; Stone, F. G. A.; Abel, E. W., Eds. Pergamon, Chap. 45.10, pp. 369-380, 1982.
  7. Miscellaneous Organoboron Compounds Negishi, E. ”Comprehensive Organometallic Chemistry”, Wilkinson, G. T.; Stone, F. G. A.; Abel, E. W., Eds. Pergamon, Chap. 45.11, pp. 381-396, 1982.
  8. Palladium-Catalyzed Reactions of Allylic Electrophiles with Organo-metallic Reagents. A Regioselective 1,4-Elimination and Regio- and Stereoselective Reduction of Allylic Derivatives Matsushita, E., and Negishi, E. J. Org. Chem. 1982, 47, 4161-4165.
  9. Biomimetic Polyene Cyclization Producing Medium- and Large-Ring Natural Products (in Japanese) Negishi, E. Kagaku Zokan (in Japanese) No. 99, p. 115-123, Nozaki, H., ed. Kagaku Dojin, Kyoto, 1983.
  10. Controlled Carbometallation. 15. Zirconium-Promoted Carbozincation of Alkynes Negishi, E.; Van Horn, D. E.; Yoshida, T.; Rand, C. L. Organometallics 1983, 2, 563-565.
  11. 1,4- and 1,5-Diketones via Palladium-Catalyzed Allylation of Potassium Enoxyborates Negishi, E.; Luo, F. T.; Pecora, A. J.; Silveira, A., Jr. J. Org. Chem. 1983, 2427-2429.
  12. Highly Regioselective Generation of ”Thermodynamic” Enolates and Their Direct Characterization by NMR Negishi, E.; Chatterjee, S. Tetrahedron Lett. 1983, 24, 1341-1344.
  13. Palladium-Catalyzed Cross-Coupling Reaction of a-Heterosubstituted Alkenylmetals. A Stereoselective Route to Heterosubstituted Dienes Suitable for the Diels-Alder Reaction Negishi, E.; Luo, F. T. J. Org. Chem. 1983, 48, 1560-1562.
  14. Countercation Effects on the Palladium-Catalyzed Allylation of Enolates Negishi, E.; John, R. A. J. Org. Chem. 1983, 48, 4098-4102.
  15. Palladium- or Nickel-Catalyzed Cross Coupling Involving Proximally Heterofunctional Reagents Negishi, E. ”Current Trends in Organo Synthesis”, Nozaki, H., ed., Pergamon, 1983, p. 269-280.
  16. A Convenient Synthesis of Unsymmetrical Bibenzyls, Homoallylarenes, and Homopropargylarenes via Palladium- Catalyzed Cross Coupling Negishi, E.; Matsushita, H.; Kobayashi, M.; Rand, C. L. Tetrahedron Lett. 1983, 24, 3823-3824.
  17. Novel Silicon-Promoted Cyclialkylation of Alkenylmetal Derivatives Negishi, E.; Boardman, L. D.; Tour, J. M.; Sawada, H.; Rand, C. L. J. Am. Chem Soc., 1983, 105, 6344-6346.
  18. Palladium-Catalyzed Acylation of Organozincs and Other Organometallics as a Convenient Route to Ketones Negishi, E.; Bagheri, V.; Chatterjee, S.; Luo, F. T.; Miller, J. A.; Stoll, A. T. Tetrahedron Lett. 1983, 24, 5181-5184.
  19. Novel Syntheses of Silylcyclopentene Derivatives via Regio- and Stereo-selective Allylzincation of Alkynes Negishi, E.; Miller, J. A. J. Am. Chem. Soc. 1983, 105, 6761-6763.
  20. A Highly Selective Synthesis of a-Alkylidenetetrahydrofurans and ?-Alkylidenebutyrolactones via Intramolecular Opening of Epoxysilanes Luo, F. T.; Negishi, E. J. Org. Chem. 1983, 48, 5144-5146.
  21. Cyclic Carboalumination of Alkynylsilanes Forming Exocyclic Alkenes Miller, J. A.; Negishi, E. Israel J. Chem. 1984, 24, 76-81.
  22. A General Method for the Preparation of Terminal and Internal Conjugated Diynes via the Palladium Catalyzed Cross Coupling Negishi, E.; Okukado, N.; Lovich, S. F.; Luo, F. T. J. Org. Chem. 1984, 49, 2629-2632.
  23. Reaction of Alkenes and Dienes with t-Butylmagnesium Halides and Zirconoene Dihalides. A Convenient Procedure for Hydrozirconation and a Novel t-Butylzirconation of Conjugated Alkenes Negishi, E.; Miller, A. J.; Yoshida, T. Tetrahedron Lett. 1984, 25, 3407-3410.
  24. Palladium-Catalyzed Synthesis of 1,4-Dienes by Allylation of Alkenylalanes: a-Farnesene Matsushita, H., and Negishi, E. Org. Synth. 1984, 63, 31-38.
  25. Mechanistic Duality in Cyclialkylation of Alkenylmetal Derivatives Boardman, L. D.; Bagheri, V.; Sawada, H.; Negishi, E. J. Am. Chem. Soc. 1984, 106, 6105-6107.
  26. Zirconium-Catalyzed Allylalumination and Benzylalumination of Alkynes Miller, J. A.; Negishi, E. Tetrahedron Lett. 1984, 25, 5863-586
  27. Formation of Carbon-Carbon and Carbon-Hetero Atom Bonds via Organo-boranes and Organoborates Negishi, E., and Idacavage, M. J. Org. React. 1985, 33, 1-246.
  28. Polycyclic Hydroboration of Acyclic and Cyclic Trienes. Reexamination of the Structures of Perhydro-9b-boraphenalenes Brown, H. C.; Negishi, E.; Dickason, W. C. J. Org. Chem. 1985, 50, 520-527.
  29. Palladium-Catalyzed Cyclization via Intramolecular Allylation of Alkenylmetals Chatterjee, S.; Negishi, E. J. Organometal. Chem. 1985, 285, C1-C4.
  30. Palladium-Catalyzed Reaction of Organometals with Allylic Acetals and Orthoesters ad Conjugate Addition Equivalents Chatterjee, S.; Negishi, E. J. Org. Chem. 1985, 50, 3406-3408.
  31. Zirconium-Promoted Bicyclization of Enynes Negishi, E.; Holmes, S. J.; Tour, J. M.; Miller, J. A. J. Am. Chem. Soc. 1985, 107, 2568-2569.
  32. Palladium-Catalyzed Allylation of Lithium 3-Alkenyl-1-Cyclopentenolates-Triethylborane and Its Application to a Selective Synthesis of Methyl (Z)-Jasmonate Luo, F. T.; Negishi, E. Tetrahedron Letter 1985, 26, 2177-2180.
  33. Organozirconium Compounds as New Reagents and Intermediates Negishi, E.; Takahashi, T. Aldrichim. Acta 1985, 18, 31-48.
  34. Conversion of Methyl Ketones into Terminal Alkynes. (E)-Buten-3-ynyl-2,6,6-trimethyl-1-cyclohexene Negishi, E.; King, A. O.; Tour, J. M. Org. Synth. 1986, 64, 44-49.
  35. Carbometallation Reaction of Alkynes with Organoalane-Zirconocene Derivatives as a Route to Stereo- and Regio- Defined Trisubstituted Alkenes Negishi, E.; Van Horn, D. E.; Yoshida, T. J. Am. Chem. Soc. 1985, 107, 6639-6647.
  36. A Mild and Selective Synthesis of Cyclopropene and Cyclopropane Derivatives via Cycliallylation of Alkenyllithiums Stoll, A. T.; Negishi, E. Tetrahedron Lett. 1985, 26, 5671-5674.
  37. A Selective Synthesis of 11-Deoxyprostaglandin E2 Methyl Ester and Its 15-Epimer Luo, F. T.; Negishi, E. J. Org. Chem. 1985, 50, 4762-4766.
  38. Controlled and Catalytic Acylpalladation. A Novel Route to Cyclopentenone and Cyclohexenone Derivatives Tour, J. M.; Negishi, E. J. Am. Chem. Soc. 1985, 107, 8289-8291.
  39. Synthesis of Cyclopentenones and Cyclohexeneones via Cycliacylation of Lithioalkenylcarboxamides Sawada, H.; Webb, M. B.; Stoll, A. T.; Negishi, E. Tetrahedron Lett. 1986, 27, 775-778.
  40. On the Origin of the Configurational Instability of 1-Silyl-1-alkenyllithiums and Related Alkenylmetals Negishi, E.; Takahashi, T. J. Am. Chem. Soc. 1986, 108, 3402-3408.
  41. Reaction of Zirconocene Dichloride with Alkyllithiums or Alkyl Grignard Reagents as a Convenient Method for Generating a ”Zirconocene” Equivalant and its use in Zirconium-Promoted Cyclization of Alkenes, Alkynes, Dienes, Enynes, and Diynes Negishi, E.; Cederbaum, F. E.; Takahashi, T. Tetrahedron Lett. 1986, 27, 2829-2832.
  42. Complete Reversal of Regiochemistry in Cyclic Acylpalladation. Novel Synthesis of Quinones Negishi, E.; Tour, J. M. Tetrahedron Lett. 1986, 27, 4869-4872.
  43. ”Bis(triphenylphosphine)palladium”: Its Generation, Characterization, and Reactions Negishi, E.; Takahashi, T.; Akiyoshi, K. J. Chem. Soc., Chem. Commun. 1986, 1338-1339.
  44. A Selective Method for the Synthesis of Stereodefined Exocyclic Alkenes via Allylmetallation of Propargyl Alcohols Negishi, E.; Zhang, Y.; Cederbaum, F. E.; Webb, M. B. J. Org. Chem. 1986, 51, 4080-4082.
  45. Potassium (2-Methyl-1-cyclohexenyloxy)triethylborate Negishi, E.; Chatterjee, S. Organometal. Synth. 1986, 3, 453-455.
  46. (E)-2-Phenyl-1-propenyldimethylalane via Zirconium-Catalyzed Carboalumination of Phenylethyne Negishi, E.; Van Horn, D. E. Organometal. Synth. 1986, 3, 467-471.
  47. (2E)-1-Trimethylsilyl-3,7-dimethyl-2,6-octadiene (Geranyltrimethylsilane) Negishi, E.; Luo, F. T. Organometal. Synth. 1986, 3, 544-546.
  48. Vinylic Organoboranes. 6. A General Stereospecific Synthesis of (E)-Disubstituted Alkenes via Hydroboration-Base- Induced Migration-Protonolysis of 1-Halo-1-Alkynes Brown, H. C.; Basavaiah, D.; Kulkarni, S. U.; Lee, H. D.; Negishi, E. and Katz, J.-J. J. Org. Chem. 1986, 51, 5270-5276.
  49. Zirconium-Promoted Bicyclization of Enynes. Effects of Enyne Structure. Negishi, E.; Swanson, D. R.; Cederbaum, F. E.; Takahashi, T. Tetrahedron Lett. 1987, 28, 917-920.
  50. Palladium- or Nickel-Catalyzed Reactions of Alkenylmetals with Unsaturated Organic Halides as a Selective Route to Arylated Alkenes and Con jugated Dienes: Scope, Limitations, and Mechanism Negishi, E.; Takahashi, T.; Baba, S.; Van Horn, D. E.; Okukado, N. and Luo, F. T. J. Am. Chem. Soc. 1987, 109, 2393-2401.
  51. Controlled Carbometallation as a New Tool for Carbon-Carbon Bond Formation and Its Application to Cyclization Negishi, E. Acc. Chem. Res. 1987, 20, 65-72.
  52. Zirconacyclopropanes and Zirconacyclopropenes: Their Synthesis, Characterization, and Reactions Takahashi, T.; Swanson, D. R.; Negishi, E. Chem. Lett. 1987, 623-626.
  53. Highly Selective Methods for a-Alkenylation and a-Arylation of Ketones via Palladium- or Nickel-Catalyzed Alkenyl- Alkenyl Coupling Negishi, E. and Akiyoshi, K. Chem. Lett. 1987, 1007-1010.
  54. Inhibition of Reductive Elimination of Diorganopalladium Species by Formation of Tetraorganopalladates Negishi, E.; Akiyoshi, K.; Takahashi, T. J. Chem. Soc., Chem. Commun. 1987, 477-478.
  55. Palladium-Catalyzed or -Promoted Reductive Carbon-Carbon Coupling. Effects of Phosphines and Carbon Ligands Negishi, E.; Takahashi, T.; Akiyoshi, K. J. Organomet. Chem. 1987, 334, 181-194.
  56. Highly Stereoselective Synthesis of Exocyclic Alkenes via Cyclialkylation Negishi, E.; Zhang, Y.; Bagheri, V. Tetrahedron Lett. 1987, 28, 5793-5796.
  57. Alkylation and Allylation of Lithium Arylborates. Factors Affecting the Di/Mono Substitution Ratio Negishi, E.; Merrill, R. E.; Abramovitch, A.; Campbell, D. P. Bull. Korean Chem. Soc. 1987, 8, 424-425.
  58. Palladium-Catalyzed Synthesis of Conjugated Dienes. (5E,7E)- and (5Z,7E)-5,7- Hexadeadienes Negishi, E.; Takahashi, T.; Baba, S. Org. Synth. 1987, 66, 60-66.
  59. 2-Methyl-4’-nitrobiphenyl. Synthesis of Biaryls via Palladium- or Nickel-Catalyzed Cross Coupling Negishi, E.; Takahashi, T.; King, A. O. Org. Synth. 1987, 66, 67-74.
  60. A Novel Bicyclization Methodology via Cyclialkylation of ?-Halo-1-metallo-1-alkynes Containing Aluminum and Zinc Negishi, E.; Sawada, H.; Tour, J. M.; Wei, Y. J. Org. Chem. 1988, 53, 913-915.
  61. Organozirconium Compounds in Organic Synthesis Negishi, E.; Takahashi, T. Synthesis, 1988, 1, 1-19.
  62. Novel 1,2-Migration Reactions of Organometals Containing Aluminum, Zinc, and Other Main Group Metals with a-Haloorganolithiums Negishi, E.; Akiyoshi, K. J. Am. Chem. Soc. 1988, 110, 646-647.
  63. One-Pot Conversion of Alkynes and Alkenes into One-Carbon Homologated Aldehydes via Hydrozirconation-Isocyanide Insertion-Hydrolysis Negishi, E.; Swanson, D. R.; Miller, S. R. Tetrahedron Lett. 1988, 29, 1631-1634.
  64. Aspects of Cross-Coupling Reactions Catalyzed by Palladium and Nickel Complexes Negishi, E.; Takahashi, T.; Akiyoshi, K. ”Catalysis of Organic Reactions,” Rylander, P. N.; Greenfield, H.; Augustine, R. L., Eds., Mercel Dekker, New York, 1988, p. 381-407.
  65. Novel Silicon-Promoted Cyclialkylation of ?-Halo-1-alkenylmetals Derivatives. Synthetic Scope and Mechanism Negishi, E.; Boardman, L. D.; Sawada, H.; Bagheri, V.; Stoll, A. T.; Tour, J.M.; Rand, C. L. J. Am. Chem. Soc. 1988, 110, 5383-5396.
  66. Efficient Synthesis of Carbobicyclic and Carbopolycyclic Compounds via Intramolecular carbopalladation Catalyzed by Palladium-Phosphine Complex Negishi, E.; Zhang, Y.; O’Connor, B. Tetrahedron Lett. 1988, 29, 2915-2918.
  67. Palladium-Catalyzed Cyclization of Alkenyl and Aryl Halides Containing a,ß-Unsaturated Carbonyl Groups via Intramolecular Carbopalladation O’Connor, B.; Zhang, Y.; Negishi, E.; Luo, F. T.; Cheng, J. W. Tetrahedron Lett. 1988, 29, 3903-3906.
  68. Palladium-Catalyzed Procedures for [3+2] Annulation via Intramolecular Alkenyl- and Arylpal¬ladation Zhang, Y.; O’Connor, B.; Negishi, E. J. Org. Chem. 1988, 53, 5588-5590.
  69. Palladium-Catalyzed Cyclic Acylmetallation of Allylic Electrophiles as a Route to Cyclopentene Derivatives Negishi, E.; Wu, G.; Tour, J. M. Tetrahedron Lett. 1988, 29, 6745-6748.
  70. Organometallic Compound Negishi, E. 1989 Yearbook of Science and Technology, McGraw-Hill, New York, 1988, p. 262-267.
  71. Synthesis of Benzofurans, Tetrahydrobenzofurans, and Related Cyclic Ethers via Cyclic Carbopalladation Negishi, E.; Nguyen, T.; O’Connor, B.; Evans, J. M.; Silveira, A., Jr. Heterocycles, 1989, 28, 55-58.
  72. Organic Syntheses Using Zirconium Compounds – Recent Developments (in Japanese) Negishi, E.; Takahashi, T. J. Synth. Org. Chem., Japan 1989, 47, 2-10.
  73. Synthesis of Cyclopentanol Derivatives via Palladium-Catalyzed Cyclic Allylpalladation-Dehydropalladation Negishi, E.; Iyer, S.; Rousset, C. J. Tetrahedron Lett. 1989, 30, 291-294.
  74. Transition Metal-Promoted Carbon-Carbon Bond Formation Involving a- and ? Heterosubstituted Carbanions Negishi, E.; Akiyoshi, K.; O’Connor, B.; Takagi, K.; Wu, G. J. Am. Chem. Soc. 1989, 111, 3089-3091.
  75. Novel Bicyclization of Enynes and Diynes Promoted by Zirconocene Derivatives and Conversion of Zirconabicycles into Bicyclic Enones via Carbonylation Negishi, E.; Holmes, S. E.; Tour, J. M.; Miller, J. A.; Cederbaum, F. E.; Swanson, D. R.; Takahashi, T. J. Am. Chem. Soc. 1989, 111, 3336-3346.
  76. Palladium-Catalyzed Cascade Carbometallation of Alkynes and Alkenes as an Efficient Route to Cyclic and Polycyclic Structures Zhang, Y.; Negishi, E. J. Am. Chem. Soc. 1989, 111, 3454-3456.
  77. Zirconocene-Olefin Complexes: An X-Ray Structure and A Novel Preparative Method Takahashi, T.; Murakami, M.; Kunishige, M.; Saburi, M.; Uchida, Y.; Kozawa, K.; Uchida, T.; Swanson, D. R.; Negishi, E. Chem. Lett. 1989, 761-764.
  78. Carbon-Carbon Bond Formation via Opening of Epoxysilanes with Organometals Containing Lithium and Copper Zhang, Y.; Miller, J. A.; Negishi, E. J. Org. Chem. 1989, 54, 2043-2044.
  79. Palladium-Catalyzed Cyclization of Benzyl Halides and Related Electrophiles Containing Alkenes and Alkynes as a Novel Route to Carbocycles Wu, G.; Lamaty, F.; Negishi, E. J. Org. Chem. 1989, 54, 2507-2508.
  80. Preparation of a Hafnocene-Ethylene Complex from Bis(?5-cyclopentadienyl)- hafnacyclopentane and Its Characterization Takahashi, T.; Tamura, M.; Saburi, M.; Uchida, Y.; Negishi, E. J. Chem. Soc., Chem. Commun. 1989, 852-853.
  81. The Formation of the Carbon-Boron Bond from Organoboranes Negishi, E. ”Inorganic Reactions and Methods”, Vol. 10, Zuckerman, J. J.; Hagen, A. D., Eds., VCH Publishers, Inc., New York, 1989, p. 91-118.
  82. Metal-Organic Approach to the Stereoselective Synthesis of Exocyclic Alkenes Negishi, E. Advan. Metal-Org. Chem. 1989, 1, 177-207
  83. Regio- and Diastereoselective Alkyl-Alkene and Alkene-Alkene Coupling Promoted by Zirconocene and Hafnocene Swanson, D. R.; Rousset, C. J.; E. Negishi.; Takahashi, T.; Seki, T,; Saburi, M.; Uchida, Y. J. Org. Chem. 1989, 54, 3521-3523.
  84. Carbonylative Cyclization via Intramolecular Trapping of Acylmetal Derivatives by Carbon Nucleophiles Catalyzed by Late Transition Metals Negishi, E.; Zhang, Y., Shimoyama, I.; Wu. G. J. Am. Chem. Soc. 1989, 111, 8018-8020.
  85. Zirconocene-Promoted Stereoselective Bicyclization of 1,6- and 1,7-Dienes to Produce trans-Zirconabicyclo[3.3.0] octanes and cis-Zirconabicyclo[4.3.0.]onanes Rousset, C. J.; Swanson, D. R.; Lamaty, F.; Negishi, E. Tetrahedron Lett. 1989, 30, 5105-5108.
  86. Stereoselective Synthesis of Exocyclic Alkenes via Zirconium-Promoted Alkyl-Diene Coupling Negishi, E.; Miller, S. R. J. Org. Chem. 1989, 54, 6014-6016.
  87. Cyclization, Coupling, and Rearrangement Reactions of Organozirconium and Related Compounds Ei-ichi Negishi Chimica Scripta 1989, 29, 457-468.
  88. Selective Skeletal Rearrangement by Carbon-Carbon Bond Activation Takahashi, T.; Fujimori, T.; Seki, T.; Saburi, M.; Uchida, Y.; Rousset, C. J.; Negishi, E. J. Chem. Soc., Chem. Commun. 1990, 182-183.
  89. Stereoselective Cyclic Carbolithiation of Alkyne Derivatives. A Stereoselective Synthesis of Exocyclic Alkenes Wu, G.; Cederbaum, F. E.; Negishi, E. Tetrahedron Lett. 1990, 31, 493-496.
  90. Synthesis of Enol Esters via Palladium-Catalyzed Carbonylation of Aryl and Alkenyl Halides Shimoyama, I.; Zhang, Y.; Wu, G.; Negishi, E. Tetrahedron Lett. 1990, 31, 2841-2844.
  91. Effects of Organometals on the Palladium-Catalyzed Tandem Carbopalladation-Cross Coupling for Preparing Stereodefined Exocyclic Alkenes Negishi, E.; Noda, Y.; Lamaty, F.; Vawter, E. J. Tetrahedron Lett. 1990, 31, 4393-4396.
  92. Nondissociative Mechanism for Decomposition of Dialkylzirconocenes to produce Alkene-Zirconocene-Phosphine Complexes Negishi, E.; Swanson, D. R.; Takahashi, T. J. Chem. Soc., Chem. Commun. 1990, 18, 1254-1255.
  93. Clean and Convenient Procedure for Converting Primary Alkyl Iodides and a,? Diiodoalkanes into the Corresponding Alkyllithium Derivatives by Treatment with t-Butyllithium Negishi, E.; Swanson, D. R.; Rousset, C. J. J. Org. Chem. 1990, 55, 5406-5409.
  94. Palladium-Catalyzed One-Step Tri- and Tetracyclization of Acyclic Polyenynes. A Novel Route to a Steroidal Skeleton Zhang, Y.; Wu, G.; Agnel, G.; Negishi, E. J. Am. Chem. Soc. 1990, 112, 8590-8592.
  95. Reaction of Dimethylzirconocene with Alkylmagnesium Halides as a Potentially General Method for Preparing Zirconocene-Alkene Complexes Takahashi, T.; Nitto, Y.; Seki, T.; Saburi, M.; Negishi, E. Chem. Lett. 1990, 2259-2262.
  96. Novel Zirconium-Promoted Carbon-Carbon Bond Formation via a 1,2-Migration Reaction of Alkynylzirconium Derivatives Takagi, K.; Rousset, C. J.; Negishi, E. J. Am. Chem. Soc. 1991, 113, 1440-1442.
  97. General and Convenient Procedure for the Preparation of Zirconocene Complexes of Alkenes and Conjugated Dienes Swanson, D. R.; Negishi, E. Organometallics 1991, 10, 825-826.
  98. A Convenient Procedure for Hydrozirconation of Alkynes with i-BuZrCp2Cl Generated in Situ by Treatment of Cp2ZrCl2 with t-BuMgCl Swanson, D. R.; Nguyen, T.; Noda, Y.; Negishi, E. J. Org. Chem. 1991, 56, 2590-2591.
  99. Remarkably ”Pair” -Selective and Regioselective Carbon-Carbon Bond Forming Reaction of Zirconacylclopentane Derivatives with Grignard Takahashi, T.; Seki, T.; Nitto, Y.; Saburi, M.; Rousset, C. J.; Negishi, E. J. Am. Chem. Soc. 1991, 113, 6266-6268.
  100. Highly Stereoselective Synthesis of Conjugated E,E- and E,Z-Dienes, E-Enynes, and E-1,2,3-Butatrienes via Alkenylborane Derivatives Negishi, E.; Yoshida, T.; Abramovitch, A.; Lew, G.; Williams, R. M. Tetrahedron 1991, 47, 343-356.
  101. Zirconium-promoted Bicyclization of Enynes Negishi, E. ”Comprehensive Organic Synthesis”, Vol. 5, Paquette, L. A., Ed., Pergamon, 1991, 1163-1184.
  102. Strictly Regio-Controlled Method for a-Alkenylation of Cyclic Ketones via Palladium-Catalyzed Cross Coupling Negishi, E.; Owczarczyk, Z.; Swanson, D. R. Tetrahedron Lett. 1991, 32, 4453-4456.
  103. Highly Stereo- and Regiocontrolled Cyclopentannulation via Allylphosphonate Conjugate Addition and Hydroboration- Oxidation-Elimination. Synthesis of Pentalenic Acid with Virtually Complete Stereo- and Regiocontrol Agnel, G.; Negishi, E. J. Am. Chem. Soc. 1991, 113, 7424-7426.
  104. Zirconium-Catalyzed, Highly Regioselective Hydrosilation Reaction of Alkenes and X-Ray Structures of Silyl(hydrido) zirconocene Derivatives Takahashi, T.; Hasegawa, M.; Suzuki, N.; Saburi, M.; Rousset, C. J.; Fanwick, P. E.; Negishi, E. J. Am. Chem. Soc. 1991, 113, 8564-8566.
  105. Catalytic Hydrogenation of Alkenes Using Zirconocene-Alkene Complexes Takahashi, T.; Suzuki, N.; Kageyama, M.; Nitto, Y.; Saburi, M.; Negishi, E. Chem. Lett. 1991, 1579-1582.
  106. Highly Selective Synthesis of Vitamin A and its Derivatives. Critical Comparison of Some Known Palladium- Catalyzed Alkenyl-Alkenyl Coupling Reactions Negishi, E.; Owczarczyk, Z. Tetrahedron Lett. 1991, 32, 6683-6686.
  107. Palladium-Catalyzed Carbonylative Cyclization of o-Allylbenzyl Halides to Produce Benzo-Annulated Enol Lactones and/or Bicyclo[3.3.0]hept-3-en-6-ones. An Efficient Route to U-68,215 Wu, G.; Shimoyama, I.; Negishi, E. J. Org. Chem. 1991, 56, 6506-6507.
  108. Carbon-Carbon Bond Formation by the Reaction of Organolithiums with a-Lithiated Cyclic Enol Ethers. Stereoselective Synthesis of ß- and ?-Hydroxy Di- and Tri-Substituted Alkenes Nguyen, T.; Negishi, E. Tetrahedron Lett. 1991, 32, 5903-5906.
  109. Novel Head-to-Tail Alkyl-Alkene or Alkene-Alkene Coupling via Zirconium-Catalyzed Reaction of Alkylmagnesium Derivatives with Monosubstituted Alkenes Rousset, C. J.; Negishi, E.; Suzuki, N.; Takahashi, T. Tetrahedron Lett. 1992, 33, 1965-1968.
  110. Zipper-Mode Cascade Carbometallation for Construction of Polycyclic Structures Negishi, E. Pure Appl. Chem. 1992, 74, 323-334.
  111. Zirconocene-Alkene Complexes: Their Formation, Structure, and Reactions Negishi, E.; Takahashi, T. Rev. Heteroatom Chem. 1992, 6, 177-201.
  112. Diastereoselective Zirconocene-Promoted Bicyclization-Carbonylation of Allylically Methyl-Substituted Enynes. Synthesis of (+)-Iridomyrmecin Agnel, G.; Owczarczyk, Z.; Negishi, E. Tetrahedron Lett. 1992, 33, 1543-1546.
  113. Cyclization Reactions of ?-Tosyloxy-1-alkynyl- and ?-Tosyloxy-1-alkenylborates and Their ?-Halo Analogues Negishi, E.; Nguyen, T.; Boardman, L. D.; Sawada, H.; Morrison, J. A. Heteroatom Chem., 1992, 3, 293-302.
  114. Cyclic Cascade Carbopalladation Reactions as a Route to Benzene and Fulvene Derivatives Negishi, E.; Harring, L. S.; Owczarczyk, Z.; Mohamud, M. M.; Ay, M. Tetrahedron Lett., 1992, 33, 3253-3256.
  115. (42) 214. Factors Affecting the Unusual Reactivity Order in the ß-Hydrogen Abstraction of Dialkylzirconocenes Negishi, E.; Nguyen, T.; Maye, J. P.; Choueiri, D.; Suzuki, N.; Takahashi, T. Chem. Lett. 1992, 2367-2370.
  116. Apparent Endo-Mode Cyclic Carbopalladation with Inversion of Alkene Configuration via Exo-Mode Cyclization- Cyclopropanation-Rearrangement Owczarczyk, Z.; Lamaty, F.; Vawter, E. J.; Negishi, E. J. Am. Chem. Soc. 1992, 114, 10091-10092.
  117. Facile Cleavage of the C-C? Bond of Zirconacyclopentenes. Convenient Method for Selectively Coupling Alkynes with Alkynes, Nitriles, and Aldehydes. Takahashi, T.; Kageyama, M.; Denisov, V.; Hara, R.; Negishi, E. Tetrahedron Lett. 1993, 34, 687-690.
  118. Highly Stereoselective and General Synthesis of (Z)-3-Methyl-2-alken-1-ols via Palladium-Catalyzed Cross Coupling of (Z)-3-Iodo-2-buten-1-ol with Organozincs and Other Organometals. Negishi, E.; Ay, M.; Gulevich, Y. V.; Noda, Y. Tetrahedron Lett. 1993, 34, 1437-1440.
  119. Selective Synthesis of Benzene Derivatives via Palladium-Catalyzed Cascade Carbometallation of Alkynes Negishi, E.; Ay, M.; Sugihara, T. Tetrahedron, 1993, 49, 5471-5482.
  120. Conversion of Non-conjugated Dienes into Conjugated Diene-Zirconocenes via Multipositional Regioisomerization Maye, J. P. and Negishi, E. Tetrahedron Lett. 1993, 34, 3359-3362.
  121. Zirconium Catalyzed C-C Bond Formation Reaction of Conjugated Diynes with EtMgBr Takahashi, T; Aoyagi, K.; Denisov, V.; Suzuki, N.; Choueiry, D.; Negishi, E. Tetrahedron Lett., 1993, 34, 8301-8304.
  122. Convenient Synthesis of Diene-Zirconocenes and Regioselective Partial Reduction of the More Highly Substituted Double Bonds of Conjugated Dienes via Complexation with Zirconocenes and Protonolysis Maye, J. P.; Negishi, E. J. Chem. Soc. Chem. Commun., 1993, 1830-1831.
  123. Palladium-Catalyzed Carbonylative Cyclization via Trapping of Acylpalladium Derivatives with Internal Enolates. Its Scope and Factors Affecting the C-to-O Ratio Negishi, E.; Copéret, C.; Sugihara, T.; Shimoyama, I.; Zhang, Y.; Wu, G.; Tour, J. M. Tetrahedron, 1994, 50, 425-436.
  124. Reaction of 3-Zircona-1-cyclopentenes and Zirconacyclopentanes with Aldehydes. A Selective and Convenient Synthesis of 4-Penten-1-ols, (Z)-5-Iodo-4-penten-1-ols, and Related Alkanols Copéret, C., Negishi, E.; Xi, Z.; Takahashi, T. Tetrahedron Lett., 1994, 35, 695-698.
  125. Isolation and Characterization of the Ethylene-Bridged Zirconocene Complex (Cp2ZrMe)2(CH2CH2) Takahashi, T.; Kasai, K.; Suzuki, N.; Nakajima, K.; Negishi, E. Organometallics, 1994, 13, 3413-3414.
  126. Patterns of Stoichiometric and Catalytic Reactions of Organozirconium and Related Complexes of Synthetic Interest Negishi, E.; Takahashi, T. Acc. Chem. Res., 1994, 27, 124-130.
  127. Deferred Carbonylative Esterification in the Pd-Catalyzed Cyclic Carbometallation-Carbonylation Cascade Sugihara, T.; Copéret, C.; Owczarczyk, Z.; Harring, L. S.; Negishi, E. J. Am. Chem. Soc., 1994, 116, 7923-7924.
  128. Facile Formation of Seven- and Eight-Membered Cycloalkenes via Catalytic and Cyclic Carbopalladation of Allenes Ma, S.; Negishi, E. J. Org. Chem., 1994, 59, 4730-4732.
  129. Titanium-Catalyzed Cascade Carboalumination of Dienes and Trienes Negishi, E.; Jensen, M. J.; Kondakov, D. Y.; Wang, S. J. Am. Chem. Soc., 1994, 116, 8404-8405.
  130. Nonconcerted Paths for Reactions of Alkene-Zirconocene Complexes Negishi, E.; Choueiry, D.; Nguyen, T. B.; Swanson, D. R.; Suzuki, N.; Takahashi, T. J. Am. Chem. Soc., 1994, 116, 9751-9752.
  131. Novel Structures and Reaction Patterns in Organozirconium and Related Chemistry Negishi, E. Seminars in Organic Synthesis: XIX Summer School ”A. Corbella”, Società Chimica. Italiana, 1994, p. 7-24.
  132. Termination of Carbopalladation of Alkynes via Carbonylative Amidation Producing Lactams Copéret, C.; Sugihara, T.; Negishi, E. Tetrahedron Lett., 1995, 36, 1771-1774.
  133. Stoichiometric Reactions of Nonconjugated Dienes with Zirconocene Derivatives. Further Delineation of the Scope of Bicyclization and Observation of a Novel Multipositional Alkene Regioisomerization Negishi, E.; Maye, J. P.; Choueiry, D. Tetrahedron, 1995, 51, 4447-4462.
  134. Acylpalladation of Internal Alkynes and Palladium-Catalyzed Carbonylation of (Z)-ß-Iodoenones Related Derivatives Producing ?-Lactones and ?-Lactams Copéret, C.; Sugihara, T.; Wu, G.; Shimoyama, I.; Negishi, E. J. Am. Chem. Soc., 1995, 117, 3422-3431.
  135. Palladium-Catalyzed Cyclization of ?-Haloallenes. A New General Route to Common, Medium, and Large Ring Compounds via Cyclic Carbopalladation Ma, S.; Negishi, E. J. Am. Chem. Soc., 1995, 117, 6345-6357
  136. Zirconium-Catalyzed Enantioselective Methylalumination of Monosubstituted Alkenes Kondakov, D.; Negishi, E. J. Am. Chem. Soc., 1995, 117, 10771-10772.
  137. 1-Chloro-2-iodoethylene. Negishi, E.; Copéret, C. ”Encyclopedia of Reagents for Organic Synthesis”, Paquette, L. A., ed. Wiley, New York, 1995, Vol. 2, 1142-1143.
  138. n-Butyllithium-Dichlorobis(?5-cyclopentadienyl)zirconium. Di(n-butyl)zirconocene. Negishi, E. ”Encyclopedia of Reagents for Organic Synthesis”, Paquette, L. A., ed. Wiley, New York, 1995, Vol. 3, 1593-1596.
  139. Trimethylaluminum-Dichlorobis(?5-cyclopentadienyl)titanium. Negishi, E.; Choueiry, D. ”Encyclopedia of Reagents for Organic Synthesis”, Paquette, L. A., ed. Wiley, New York, 1995, Vol. 7, 5190-5192.
  140. Trimethylaluminum-Dichlorobis(?5-cyclopentadienyl)zirconium. Negishi, E.; Choueiry, D. ”Encyclopedia of Reagents for Organic Synthesis”, Paquette, L. A., ed. Wiley, New York, 1995, Vol. 7, 5192-5195.
  141. The Synthesis of Vinyl- and Arylmetals Negishi, E.; Choueiry, D. ”Organic Functional Group Transformations,” Katritzky, A. R.; Meth-Cohn, O.; Rees, C. W., eds., Pergamon Press, Oxford, 1995, Vol. 2, 951-995.
  142. Cyclic Carbopalladation. A Versatile Synthetic Methodology for the Construction of Cyclic Organic Compounds Negishi, E.; Copéret, C.; Liou, S. Y.; Liu, F.; Ma, S. Chem. Rev., 1996, 96, 365-393.
  143. Zirconium-Catalyzed Enantioselective Alkylalumination of Monosubstituted Alkenes Proceeding via Noncyclic Mechanism Kondakov, D. Y.; Negishi, E. J. Am. Chem. Soc.,1996, 118, 1577-1578.
  144. Palladium-Catalyzed Carbonylative Cyclization of 1-Iodo-2-alkenylbenzenes Negishi, E.; Copéret, C.; Ma, S.; Mita, T.; Sugihara, T.; Tour, J. M. J. Am. Chem. Soc., 1996, 118, 5904-5918.
  145. Palladium-Catalyzed Cyclization of 1-Iodo-Substituted 1,4-, 1,5-, and 1,6-Dienes as Well as of 5-Iodo-1,5-dienes in the Presence of Carbon Monoxide Negishi, E.; Ma, S.; Amanfu, J.; Copéret, C.; Miller, J. A.; Sugihara, T.; Tour, J. M. J. Am. Chem. Soc., 1996, 118, 5919-5931.
  146. Titanium-Catalyzed Cascade Carboalumination of 2-Alkyl-Substituted Dienes and Trienes Kondakov, D. Y.; Wang, S.; Negishi, E. Tetrahedron Lett., 1996, 37, 3803-3806.
  147. Facile and Reversible Formation of Monocyclopentadienylzirconium Derivatives by the Reaction of Cp2ZrCl2 with Alkyllithiums and Their Reactions with Electrophiles and Olefins Kondakov, D. Y.; Negishi, E. J. Chem. Soc., Chem. Commun., 1996, 963-964.
  148. Palladium-Catalyzed Cascading Carbonylative Cyclization of Iodo-Dienes and -Trienes Copéret, C.; Ma, S.; Negishi, E. Angew. Chem., Int. Ed. Engl., 1996, 2125-2126.
  149. A Selective Procedure of a-Alkenylation of Enones Involving Pd-Catalyzed Alkenyl-Alkenyl Coupling and Its Application of a Convergent and Efficient Synthesis of Nakienone B Pour, M.; Negishi, E. Tetrahedron Lett., 1996, 37, 4679-4682.
  150. Cyclic Carbopalladation of Alkynes Terminated by Carbonylative Amidation Copéret, C.; Ma, S.; Sugihara, T.; Negishi, E. Tetrahedron, 1996, 52, 11529-11544.
  151. Reaction of Alkynes with Organometallic Reagents Negishi, E.; Choueiry, D. ”Preparation of Alkynes: A Practical Approach,” Williams, J. M. J., Ed., Oxford University Press, Oxford, 137-156.
  152. Multiple Mechanistic Pathways for Zirconium-Catalyzed Carboalumination of Alkynes Negishi, E.; Kondakov, D. Y.; Choueiry, D.; Kasai, K.; Takahashi, T. J. Am. Chem. Soc., 1996, 118, 9577-9588.
  153. An Odyssey from Stoichiometric Carbotitanation of Alkynes to Zirconium-Catalyzed Enantioselective Carboalumination of Alkenes Negishi, E.; Kondakov, D. Y. Chem. Soc. Rev., 1996, 26, 417-426.
  154. Convenient and General Synthesis of 1-Monoorganyl- and 1,2,-Diorganylcyclobutenes via Cyclialkylation Negishi, E.; Liu, F.; Choueiry, D.; Mohamud, M. M.; Silveira, A. Jr.; Reeves, M. J. Org. Chem., 1996, 61, 8325-8328.
  155. Efficient and Diastereoselective Synthesis of (+)-Goniobutenolide A via Palladium-Catalyzed Ene-Yne Cross Coupling-Lactonization Cascade Kotora, M.; Negishi, E. Tetrahedron Lett., 1996, 37, 9041-9042.
  156. Highly Efficient and Selective Procedures for the Synthesis of ?-Alkylidenebutenolides and Its Application to the Synthesis of Rubrolides A, C, D, and E Kotora, M.; Negishi, E. Synthesis, 1997, 121-128.
  157. An Efficient and Selective Synthesis of Nakienone A Involving a Novel Protocol of a-Alkenylation of Ketones via Palladium-Catalyzed Alkenyl-Alkenyl Coupling Pour, M.; Negishi, E. Tetrahedron Lett., 1997, 38, 525-528
  158. On the Regiochemistry of Cyclialkylation of Regiodefined 4-Halo-1-alkenylmetals Producing Cyclobutenes Liu, F.; Negishi, E. Tetrahedron Lett., 1997, 38, 1149-1152.
  159. Anti-Carbometallation of Homopropargyl Alcohols and Their Higher Homologues via Non-Chelation-Controlled Syn- Carbometallation and Chelation-Controlled Isomerization Ma, S.; Negishi, E. J. Org. Chem., 1997, 62, 784-785.
  160. Carbometallation Reactions of Diphenylacetylene and Other Alkynes with Methylalanes and Titanocene Derivatives Negishi, E.; Kondakov, D. Y.; Van Horn, D. E. Organometallics, 1997, 16, 951-957.
  161. Regio- and Stereoselective Synthesis of ?-Alkylidenebutenolides and Related Compounds Negishi, E.; Kotora, M. Tetrahedron, 1997, 53, 6707-6738.
  162. Synthesis of Hydrazulenes via Zr-Promoted Bicyclization of Enynes and Transition Metal-Catalyzed or Radical Cyclization of Alkenyl Iodides. Efficient Synthesis of (±)-7-epi-ß-Bulnesene Negishi, E.; Sugihara, T.; Ma, S.; Noda, Y. J. Org. Chem., 1997, 62, 1922-1923.
  163. Pd- or Ni-Catalyzed Cross Coupling with Organometals Containing Zn, Mg, Al, and Zr Negishi, E.; Liu, F. Chapter 1 in Cross Coupling Reactions, Stang, P. J.; Diederich, F., Eds., VCH, Weinheim, 1998, p. 1-47.
  164. Anti-Hydroalumination of Homo- and Bishomopropargyl Alcohols Ma, S.; Liu, F.; Negishi, E. Tetrahedron Lett., 1997, 38, 3829-3832.
  165. Convenient Preparative Method of a,ß-Disubstituted Cyclopentenone by Zirconocene- Promoted Intermolecular Coupling of an Alkyne, EtMgBr (or Ethylene) and CO Takahashi, T.; Xi, Z.; Nishihara, Y.; Huo, S.; Kasai, K.; Aoyagi, K.; Denisov, V.; Negishi, E. Tetrahedron, 1997, 53, 9123-9134.
  166. Direct Synthesis of Heteroarylethynes via Palladium-Catalyzed Coupling of Heteroaryl Halides with Ethynylzinc Halides. Its Application to an Efficient Synthesis of a Thiophenelactone from Chamaemelum Nobile L. Negishi, E.; Xu, C.; Tan, Z.; Kotora, M. Heterocycles, 1997, 46, 209-214.
  167. Efficient and Stereoselective Synthesis of Freelingyne via Pd-Catalyzed Cross Coupling and Lactonization Liu, F.; Negishi, E. J. Org. Chem., 1997, 62, 8591-8594.
  168. Convenient and Direct Synthesis of Terminal Alkynes via Pd-Catalyzed Cross Coupling. Critical Comparison of Countercations Kotora, M.; Xu, C.; Negishi, E. J. Org. Chem., 1997, 62, 8957-8960.
  169. Enantiomerically Pure Zirconium and Hafnium Complexes Containing a Chiral Cyclopentadiene Derivative Prepared from (-)-ß-Pinene Rousset, C. J.; Iyer, S.; Negishi, E. Tetrahedron: Asymmetry, 1997, 8, 3921-3926.
  170. Catalytic Generation and Trapping of Acylmetals Containing Ni and Cu with Enolates Negishi, E.; Makabe, H.; Shimoyama, I.; Wu, G.; Zhang, Y. Tetrahedron, 1998, 54, 1095-1106.
  171. Alkene and Alkyne Complexes at Zirconocene. Their Preparation, Structure and Novel Transformations Negishi, E.; Takahashi, T. Bull. Chem. Soc. Jpn, 1998, 71, 755-769.
  172. Carbozincation of Enynes Catalyzed by Titanium(IV) Alkoxides and Alkylmagnesium Derivatives Montchamp, J.-L.; Negishi, E. J. Am. Chem. Soc., 1998, 120, 5345-5346.
  173. Zirconium-Catalyzed and Zirconium-Promoted Cyclization Reactions of Nonconjugated Dienes with Alkylmagnesium Halides to Give Cycloalkylmethylmagnesium Derivatives Negishi, E.; Rousset, C. J.; Choueiry, D.; Maye, J. P.; Suzuki, N.; Takahashi, T. Inorg. Chim. Acta, 1998, 280/1-2, 8-20.
  174. Zirconium-Catalyzed Carboalumination of Alkynes and Enynes as a Route to Aluminacycles and Their Conversion to Cyclic Organic Compounds Negishi, E.; Montchamp, J.-L.; Anastasia, L.; Elizarov, A.; Choueiry, D. Tetrahedron Lett., 1998, 39, 2503-2506.
  175. Strictly Regio- and Stereo-Controlled a-Alkenylation of Bicyclic Enones and Their Derivatives via Palladium- Catalyzed Cross Coupling and Its Application to a Formal Synthesis of (±)-Carbacyclin Negishi, E.; Pour, M.; Cederbaum, F. E.; Kotora, M. Tetrahedron, 1998, 54, 7057-7074.
  176. Zirconocenes Negishi, E.; Montchamp, J. L. Chapter 5 in Metallocenes, Togni, A.; Halterman, R. L., Eds., VCH, Weinheim, 1998, 241-319.
  177. Selective Intermolecular Coupling of Alkynes with Nitriles and Ketones via ß, ß? Carbon-Carbon Bond Cleavage of Zirconacyclopentenes Takahashi, T.; Xi, C.; Xi, Z.; Kageyama, M.; Fischer, R.; Nakajima, K.; Negishi, E. J. Org. Chem., 1998, 63, 6802-6806.
  178. Palladium- and Nickel-Catalyzed Reactions of Organozinc Compounds Negishi, E. Chapter 11 in Organozinc Reagents: A Practical Approach, Knochel, P. and Jones, P., Ed., Oxford University Press, Oxford, 1999, 213-243.
  179. A Highly Efficient and Selective Synthesis of Lissoclinolide Featuring Hydrogen Transfer Hydrozirconation, trans- Selective Pd-Catalyzed Cross Coupling of Alkenylzirconiums with 1,1-Dibromoalkenes and Ag-Catalyzed Lactonization Providing (Z)-?-Alkylidenebutenolides Xu, C.; Negishi, E. Tetrahedron Lett., 1999, 40, 431-434.
  180. Intermolecular Trapping of Acylpalladium and Related Acylmetal Derivatives with Active C H Compounds Negishi, E.; Liou, S.-Y.; Xu, C.; Shimoyama, I.; Makabe, H. J. Mol. Cat., 1999, 143, 279-286.
  181. Principle of Activation of Electrophiles by Electrophiles through Dimeric Association – Two is Better than One Negishi, E. Chem. Eur. J., 1999, 5, 411-420.
  182. Palladium-Catalyzed Highly Diastereoselective Cyclic Carbopalladation-Carbonylative Esterification Tandem Reaction of Iododienes and Iodoarylalkenes Coperét, C.; Negishi, E. Org. Lett., 1999, 1, 165-167.
  183. Hydrogen Transfer Hydrozirconation of Alkenes with i-BuZrCp2Cl Catalyzed by Lewis-Acidic Metal Compounds Containing Al, Zn, Si, Ag, Ni, and Pd Makabe, H.; Negishi, E. Eur. J. Org. Chem. 1999, 969-971.
  184. Synthesis of a-Iodo-a,ß-unsaturated Ketones by the Reaction of a-Silyl-a,ß-unsaturated Ketones with ICl or ICl-AlCl3 Alimardanov, A.; Negishi, E. Tetrahedron Lett. 1999, 40, 3839-3842.
  185. Highly Chemo-, Regio-, and Stereoselective Carbon-Carbon Bond Formation via Migratory Insertion Reaction of Zirconacyclopentene Derivatives and Alkynylmetals Containing Li and Mg. Novel Synthesis of 1,5-Dienes and 1,5-Enynes Dumond, Y.; Negishi, E. J. Am. Chem. Soc.,1999, 121, 11223-11224.
  186. Novel and Selective a-Substitution of Ketones and Other Carbonyl Compounds Based on Pd-Catalyzed Cross Coupling of a,ß-Unsaturated Carbonyl Derivatives Containing a-Halogen or a-Metal Groups Negishi, E. J. Organomet. Chem., 1999, 576, 179-194.
  187. Novel and Selective a-Substitution of Ketones and Other Carbonyl Compounds Based on Pd-Catalyzed Cross Coupling of a,ß-Unsaturated Carbonyl Derivatives Containing a-Halogen or a-Metal Groups Negishi, E. In Perspective in Organopalladium Chemistry for the 21 Century,” Tsuji, J., Ed., Elsevier, 1999, 179-194.
  188. An Efficient and Stereoselective Synthesis of Xerulin via Pd-Catalyzed Cross Coupling and Lactonization Featuring (E)-Iodobromoethylene as a Novel Two-Carbon Synthon Negishi, E.; Alimardanov, A.; Xu, C. Org. Lett., 2000, 2, 65-67.
  189. A General Method for the Synthesis of E and/or Z Oligoisoprenoids Based on Pd-Catalyzed Homoallyl-Alkenyl and Homopropargyl-Alkenyl Cross Coupling and Zr-Catalyzed Carboalumination Negishi, E.; Liou, S. Y.; Xu, C.; Huo, S. Polyhedron, 2000, 19, 591-592.
  190. Development of a Method for the Synthesis of a-Substituted a,ß-Unsaturated Lactones Based on Stille-Type Pd- Catalyzed Carbonylation of (Z)-?-Iodoalkenols. An Efficient and Selective Synthesis of (+)-Hamabiwalactone B Liao, B.: Negishi, E. Heterocycles, 2000, 52, 1241-1249.
  191. Asymmetric Carbometallations Negishi, E. Chapter 4 in Catalytic Asymmetric Synthesis II, Ojima, I., Ed., J. Wiley-VCH, New York, 2000, 165-189.
  192. Ethylzincation of Monosubstituted Alkenes Catalyzed by EtMgBr-Cl2ZrCp2 and Palladium-Catalyzed Cross Coupling of the Resultant Diisoalkylzinc Derivatives Gagneur, S.; Montchamp, J. L.; Negishi, E. Organometallics, 2000, 19, 2417-2419.
  193. A Strictly “Pair”-Selective Synthesis of Conjugated Diynes via Pd-Catalyzed Cross Coupling of 1,3-Diynylzincs: A Superior Alternative to the Cadiot-Chodkiewicz Reaction Negishi, E.; Hata, M.; Xu, C. Org. Lett., 2000, 2, 3687-3689.
  194. Strictly Regiocontrolled a-Monosubstitution of Cyclic Carbonyl Compounds with Alkynyl and Alkyl Groups via Pd- Catalyzed Coupling of Cyclic a-Iodoenones with Organozincs Negishi, E.; Tan, Z.; Liou, S. Y.; Liao, B. Tetrahedron, 2000, 56, 10197-10207.
  195. A Novel Hydrogen Transfer Hydroalumination of Alkenes with Triisobutylaluminum Catalyzed by Pd and Other Late Transition Metal Complexes Gagneur, S.; Makabe, H.; Negishi, E. Tetrahedron Lett., 2001, 42, 785-787.
  196. Some Newer Aspects of Organozirconium Chemistry of Relevance to Organic Synthesis. Zr-Catalyzed Enantioselective Carbometallation Negishi, E. Pure Appl. Chem., 2001, 73, 239-242.
  197. A Novel, Selective, and Efficient Route to Carotenoids and Related Natural Products via Zr-Catalyzed Carboalumination and Pd- and Zn-Catalyzed Cross Coupling Zeng, F.; Negishi, E. Org. Lett., 2001, 3, 719-722.
  198. Stereoselective Synthesis of Exocyclic Alkenes via Cu-Catalyzed Allylmagnesiation, Pd-Catalyzed Alkylation, and Ru- Catalyzed Ring Closing Olefin Metathesis: Highly Stereoselective Synthesis of (Z)- and (E)-?-Bisabolenes Dumond, Y.; Anastasia, L.; Negishi, E. Eur. J. Org. Chem. 2001, 3039-3043.
  199. Highly Satisfactory Procedures for the Pd-Catalyzed Cross Coupling of Aryl Electrophiles with in Situ Generated Alkynylzinc Derivatives Anastasia, L.; Negishi, E. Org. Lett., 2001, 3, 3111-3113.
  200. A Convenient and Asymmetric Protocol for the Synthesis of Natural Products Containing Chiral Alkyl Chains via Zr- Catalyzed Asymmetric Carboalumination of Alkenes. Syntheses of Phytol and Vitamins E and K Huo, S.; Negishi, E. Org. Lett., 2001, 3, 3253-3256.
  201. Organozirconium Chemistry in Organic Synthesis Negishi, E. Chapter 8 in Organometallics in Synthesis: A Manual, 2nd Ed., Schlosser, M., Ed., Wiley, New York, 2002, 926-1002.
  202. Zirconium-Catalyzed Enantioselective Carboalumination of “Unactivated” Alkenes as a New Synthetic Tool for Asymmetric Carbon-Carbon Bond Formation Negishi, E.; Huo, S. Pure Appl. Chem. 2002, 74, 151-157.
  203. A Genealogy of Pd-Catalyzed Cross Coupling Negishi, E. J. Organomet. Chem. 2002, 653, 34-40.
  204. Synthesis and Reactivity of Zirconocene Derivatives Negishi, E.; Huo, S. Chapter 1 in Titanium and Zirconium in Organic Synthesis, Marek, I., Ed., Wiley-VCH, Weinheim, 2002, 1-49.
  205. (-)-Dichlorobis[(1,2,3,3a,7a-?)-1-[(1S,2S,5R)-5-methyl-2-(1-methylethyl)]cyclohexyl-1H- inden-1-y]zirconium and Its (+)-(1R,2R,5S)-Isomer Negishi, E.; Huo, S. “Encyclopedia of Reagents for Organic Synthesis”, Paquette, L. A., Ed., Wiley, New York, 2002.
  206. A New Protocol for the Enantioselective Synthesis of Methyl-Substituted Chiral Alkanols and Their Derivatives via Hydroalumination–Zirconium Catalyzed Alkylalumination Tandem Process Huo, S.; Shi, J.; Negishi, E. Angew. Chem. Int. Ed. 2002, 41, 2141-2143.
  207. A Novel, Highly Selective, and General Methodology for the Synthesis of 1,5-Diene-Containing Oligoisoprenoids of All Possible Geometrical Combinations Exemplified by an Iterative and Convergent Synthesis of Coenzyme Q10 Negishi, E.; Liou, S. Y.; Xu, C.; Huo, S. Org. Lett. 2002, 4, 261-264.
  208. (E)-1-Bromo-2-iodoethylene Negishi, E.; Zeng, F. In Encyclopedia of Reagents for Organic Synthesis, Paquette, L. A., Ed., John Wiley & Sons, Inc., New York, 2002.
  209. A Highly Efficient, Selective, and General Method for the Synthesis of Conjugated (all-E)-Oligoenes of the (CH=CH)n Type via Iterative Hydrozirconation–Palladium- Catalyzed Cross-Coupling Zeng, F.; Negishi, E. Org. Lett. 2002, 4, 703-706.
  210. Catalytic and Selective Conversion of (Z)-2-En-4-ynoic Acids to either 2H-Pyran-2-ones in the Presence of ZnBr2 or (Z)-5-Alkylidenefuran-2(5H)-ones in the Presence of Ag2CO3 Anastasia, L.; Xu, C.; Negishi, E. Tetrahedron Lett. 2002, 43, 5673-5676.
  211. Handbook of Organopalladium Chemistry for Organic Synthesis, 2 Vols. Negishi, E., Ed., Wiley-Interscience, New York, 2002, 3279 pp.
  212. Fundamental Properties of Palladium and Patterns of the Reactions of Palladium and Its Negishi, E. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. I.2, 17-35.
  213. General Discussion of the Methods of Synthesis and In-Situ Generation of Organopalladium Compounds Negishi, E. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. II.3.1, 127-145.
  214. Palladium-Catalyzed Aryl-Aryl Coupling Anastasia, L.; Negishi, E. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. III.2.5, 311-334.
  215. Palladium-Catalyzed Alkenyl-Aryl, Aryl-Alkenyl, and Alkenyl-Alkenyl Coupling Reactions Huo, S.; Negishi, E. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. III.2.6, 335-408.
  216. Palladium-Catalyzed Alkynylation with Alkynylmetals or Alkynyl Electrophiles Negishi, E.; Xu, C. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. III.2.8.2, 531-549.
  217. Palladium-Catalyzed Cross-Coupling between Allyl, Benzyl, or Propargyl Groups and Unsaturated Groups Negishi, E.; Liu, F. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. III.2.9, 551-589.
  218. Palladium-Catalyzed Cross-Coupling between Allyl-, Benzyl-, or Propargylmetals and Allyl, Benzyl, or Propargyl Electrophiles Negishi, E.; Liao, B. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. III.2.10, 591-596.
  219. Palladium-Catalyzed Cross-Coupling Involving Saturated Alkylmetals Negishi, E.; Gagneur, S. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. III.2.11.1, 597-618.
  220. Palladium-Catalyzed Cross-Coupling between Homoallyl-, Homopropargyl-, or Homobenzylmetals and Alkenyl or Aryl Electrophiles Negishi, E.; Zeng, F. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. III.2.11.2, 619-633.
  221. Palladium-Catalyzed a-Substitution Reactions of Enolates and Related Derivatives Other than the Tsuji-Trost Allylation Reaction Negishi, E. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. III.2.14.1, 693-719.
  222. Palladium-Catalyzed Cross-Coupling Involving ?-Hetero-Substituted Compounds Other than Enolates Negishi, E.; Alimardanov, A. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. III.2.14.2, 721-766.
  223. Palladium-Catalyzed Conjugate Substitution Negishi, E.; Dumond, Y. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. III.2.15, 767-789.
  224. Synthesis of Natural Products via Palladium-Catalyzed Cross-Coupling Tan, Z.; Negishi, E. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. III.2.18, 863-942.
  225. Palladium-Catalyzed Tandem and Cascade Carbopalladation of Alkynes and 1,1-Disubstituted Alkenes Terminated by Carbonylative Reactions Negishi, E.; Copéret, C. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. IV.3.3, 1431-1448.
  226. Pd-Catalyzed Allylation and Related Substitution Reactions of Enolates and Related Derivatives of “Ordinary” Ketones, and Aldehydes, and Other Carbonyl Compounds Negishi, E.; Liou, S. Y. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. V.2.1.4, 1769-1793.
  227. Synthesis of Natural Products via Nucleophilic Attack on ?-Ligands of Palladium-Alkene, Palladium-Alkyne, and Related ?-Complexes Xu, C.; Negishi, E. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. V.3.6, 2289-2305.
  228. Reactions of Acylpalladium Derivatives with Enolates and Related Amphiphilic Reagents Negishi, E.; Makabe, H. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. VI.2.3, 2455-2471.
  229. Intramolecular Acylpalladation Reactions with Alkenes, Alkynes, and Related Unsaturated Compounds Copéret, C.; Negishi, E. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. VI.4.1.1, 2519-2552.
  230. Palladium-Catalyzed Heterogeneous Hydrogenation King, A. O.; Larsen, R. D.; Negishi, E. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. VII.2.1, 2719-2758.
  231. Palladium-Catalyzed Isomerization of Alkenes, Alkynes, and Related Compounds without Skeletal Rearrangements Negishi, E. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. VII.3, 2783-2788
  232. Palladium-Catalyzed Hydrometallation Makabe, H.; Negishi, E. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. VII.4, 2789-2823.
  233. Other Palladium-Catalyzed or –Promoted Oxidation Reactions via 1,2- or 1,4-Elimination Fujiwara, Y.; Negishi, E. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. VIII.3.3, 2895-2903.
  234. Other Miscellaneous Palladium-Catalyzed or -Promoted Oxidation Reactions Negishi, E. In , Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. VIII.4, 2905-2912.
  235. Palladium-Catalyzed Carbon Skeletal Rearrangements Other than [3, 3] Rearrangements Negishi, E. In The Handbook of Organopalladium Chemistry for Organic Synthesis, Negishi, E., Ed., J. Wiley & Sons, New York, 2002, Sect. IX.2.1.2, 2935-2938.
  236. Organometallic Complexes of Zirconium and Hafnium Negishi, E.; Takahashi, T. Houben-Weyl, Science of Synthesis, Vol. 2, Imamoto, T.; Ed., Thieme, 2002, Chap. 2.11, 681-848.
  237. (E)-1-Bromo-4-trimethylsilyl-1-buten-3-yne and (E)-1-Bromo-4-(tert-butyldimethylsilyl)- 1-buten-3-yne Negishi, E.; Zeng, F. Encyclopedia of Reagents for Organic Synthesis, Paquette, L. A., Ed., John Wiley & Sons, Inc., New York, 2002.
  238. Highly Satisfactory Alkynylation of Alkenyl Halides via Pd-Catalyzed Cross-Coupling with Alkynylzincs and Its Critical Comparison with the Sonogashira Alkynylation Negishi, E.; Qian, M.; Zeng, F.; Anastasia, L.; Babinski, D. Org. Lett. 2003, 5, 1597-1600.
  239. Strictly “Pair”-Selective and Economical Synthesis of Conjugated Diynes via Pd-Catalyzed Reaction of Terminal Alkynes with 1,1-Dichloroethylene, Elimination with LDA, and Subsequent Transformations Qian, M.; Negishi, E. Org. Process. Res. Dev., 2003, 1, 412-417.
  240. Highly Selective Synthesis of (E)-3-Methyl-1-trialkylsilyl-3-en-1-ynes via trans-Selective Alkynylation Catalyzed by Cl2Pd(DPEphos) and Stereospecific Methylation with Methylzincs Catalyzed by Pd(tBu3P)2 Shi, J.; Zeng, X.; Negishi, E. Org. Lett., 2003, 5, 1825-1828.
  241. Palladium-Catalyzed Alkynylation Negishi, E.; Anastasia, L. Chem. Rev., 2003, 103, 1979-2017
  242. Clean Inversion of Configuration in the Pd-Catalyzed Cross-Coupling of 2-Bromo-1,3-dienes Zeng, X.; Hu, Q.; Qian, M.; Negishi, E. J. Am. Chem. Soc., 2003, 125, 13636-13637.
  243. Pd-Catalyzed Selective Tandem Arylation of 1,1-Dihalo-1-alkenes with Aryl- and Alkylzinc Derivatives to Produce a- Alkyl-substituted Styrene Derivatives Shi, J.; Negishi, E. J. Organomet. Chem., 2003, 687, 518-524.
  244. Highly Stereoselective Synthesis of (1E)-2-Methyl-1,3-dienes by Palladium-Catalyzed trans-Selective Cross-Coupling of 1,1-Dibromo-1-alkenes with Alkenylzinc Reagents Zeng, X.; Qian, M.; Hu, Q.; Negishi, E. Angew. Chem. Int. Ed. 2004, 43, 2259-2263.
  245. A New, Efficient, and General Route to Reduced Polypropionates via Zr-Catalyzed Asymmetric C–C Bond Formation Negishi, E.; Tan, Z.; Liang, B.; Novak, T. Proc. Natl. Acad. Sci. USA, 2004, 101, 5782-5787
  246. Disasteroselective, Enantioselective, and Regioselective Carboalumination Reactions Catalyzed by Zirconocene Derivatives Negishi, E.; Tan, Z. Topics in Organometallic Chemistry, Takahashi, T., Ed., Springer, 2005, 139-176.
  247. Zr-Promoted “Pair”-selective and Regioselective Synthesis of Penta-substituted Benzene Derivatives Dumond, Y. R.; Negishi, E. Tetrahedron, 2004, 60, 1345-1352
  248. An Efficient and General Method for the Synthesis of ?,?-Difunctional Reduced Polypropionates by Zr-catalyzed Asymmetric Carboalumination: Synthesis of the Scyphostatin Sidechain Tan, Z.; Negishi, E. Agnew. Chem. Int. Ed., 2004, 43, 2911-2914.
  249. Efficient and Selective Synthesis of Siphonarienolone and Related Reduced Polypropionates via Zr-Catalyzed Asymmetric Carboalumination Magnin-Lachaux, M.; Tan, Z.; Liang, B.; Negishi, E. Org. Lett., 2004, 6, 1425-1427.
  250. Use of InCl3 as a Cocatalyst and a Cl2Pd(DPEphos)–P(2-Furyl)3 Catalyst System for One-Pot Hydrometalation– Cross-Coupling and Carbometalation–Cross-Coupling Tandem Processes Qian, M.; Huang, Z.; Negishi, E. Org. Lett., 2004, 6, 1531-1534.
  251. Palladium- or Nickel-Catalyzed Cross-Coupling with Organometals Containing Zinc, Aluminum, and Zirconium: The Negishi Coupling Negishi, E.; Zeng, X.; Tan, Z.; Qian, M.; Hu, Q.; Huang, Z.; Babinski, D. J. Metal-Catalyzed C–C and C–N Coupling Reactions, de Meijere, A.; Diederich, F., Eds. Wiley-VCH, 2004, Chap. 15, p. 815-889.
  252. (13) 351. Efficient and Selective Synthesis of 6,7-Dehydrostipiamide via Zr-Catalyzed Asymmetric Carboalumination and Pd- Catalyzed Cross-Coupling of Organozincs Zeng, X.; Zeng, F.; Negishi, E. Org. Lett., 2004, 6, 3245-3248.
  253. All-Catalytic, Efficient, and Asymmetric Synthesis of ?,?-Diheterofunctional Reduced Polypropionates via “One-Pot” Zr-Catalyzed Asymmetric Carboalumination-Pd-Catalyzed Cross-Coupling Tandem Process Novak, T.; Tan, Z.; Liang, B.; Negishi, E. J. Am. Chem. Soc., 2005, 127, 2838-2839.
  254. Palladium-Catalyzed Cross-Coupling Reaction of Alkynylzincs with Benzylic Electrophiles Qian, M.; Negishi, E. Tetrahedron Lett., 2005, 46, 2927-2930.
  255. Palladium-Catalyzed Cross-Coupling Reactions with Zinc, Boron, and Indium Exhibiting High Turnover Numbers (TONs): Use of Bidentate Phosphines and Other Critical Factors in Achieving High TONs Huang, Z.; Qian, M.; Babinski, D. T.; Negishi, E. Organometallics, 2005, 24, 475-478.
  256. A Quarter of a Century of Explorations in Organozirconium Chemistry Negishi, E. Dalton Trans. 2005, 827-848.
  257. Di-n-butylbis(?5-cyclopentadienyl)zirconium Negishi, E.; Novak T. Electronic Encyclopedia of Reagents for Organic Synthesis. Paquette, L.A., Ed., John Wiley & Sons, Inc., New York, 2005.
  258. Palladium-Catalyzed Cross-Coupling of Alkynylzincs with Allylic Electrophiles: An Efficient and Selective Synthesis of Stereo- and Regio-Defined 1,4-Enynes Qian, M.; Negishi, E. Synlett, 2005, 1789-1793.
  259. Palladium-Catalyzed trans-Selective Alkynylation-Alkylation Tandem Reaction of 1,1-Dihalo-1-alkenes for the Syntehsis of (E)-3-Alkyl-1-trialkylsilyl-3-en-1-ynes Negishi, E.; Shi, J.; Zeng, X Tetrahedron, 2005, 61, 9886-9895.
  260. Palladium-Catalyzed Alkenylation via Negishi Coupling Negishi, E.; Hu, Q.; Huang, Z.; Qian, M.; Wang, G. Aldrichim. Acta, 2005, 38, 71-88.
  261. Palladium-Catalyzed Cyclization via Carbopalladation and Acylpalladation Negishi, E.; Wang, G.; Zhu, G. Topics in Organometallic Chemistry 19. Metal Catalyzed Cascade Reactions, Müller, T. J. J., Ed., Springer, Heidelberg, 2006, Vol. 19, pp. 1-48.
  262. Widely Applicable Pd-Catalyzed trans-Selective Monoalkylation of Unactivated 1,1-Dichloro-1-alkenes and Pd-Catalyzed Second Substitution for the Selective Synthesis of (E)- or (Z)-Trisubstituted Alkenes Tan, Z; Negishi, E. Angew. Chem. Int. Ed., 2006, 45, 762-765.
  263. Catalytic, Efficient, and syn-Selective Construction of Deoxypolypropionates and Other Chiral Compounds via Zr-Catalyzed Asymmetric Carboalumination of Allyl Alcohol Liang, B.; Novak, T.; Tan. Z.; Negishi, E. J. Am. Chem. Soc., 2006, 128, 2770-2771.
  264. Zirconium-Catalyzed Asymmetric Carboalumination (ZACA Reaction) of 1,4-Dienes Tan, Z.; Liang, B.; Huo, S.; Shi, J.; Negishi, E. Tetrahedron: Asymmetry, 2006, 17, 512-515.
  265. Highly Stereoselective Synthesis of the Side-Chains of Mycolactones A and B Featuring Stepwise Double Substitutions of 1,1-Dibromo-1-alkenes Yin, N.; Wang, G.; Qian, M.; Negishi, E. Angew. Chem. Int. Ed., 2006, 45, 2916-2920.
  266. Palladium- or Nickel-Catalyzed Cross-Coupling with Organozincs and Related Organometals Negishi, E.; Hu, Q.; Huang, Z.; Wang, G.; Yin, N. The Chemistry of Organozinc Compounds, Rappoport, Z.; Marek, I., Eds., John Wiley & Sons, Ltd., Chichester, England, 2006, Chap. 11, 457-553.
  267. Selective Synthesis of Epolactaene Featuring Efficient Construction of Methyl (Z)-2-lodo-2-butenoate and (2R,3S,4S)- 2-Trimethylsilyl-2,3-epoxy-4-methyl-?-butyrolactone Tan, Z.; Negishi, E. Org. Lett., 2006, 8, 2783-2785.
  268. A Convenient and Genuine Equivalent to HZrCp2Cl Generated in Situ from ZrCp2Cl2–DlBAL-H Huang, Z.; Negishi, E. Org. Lett., 2006, 8, 3675-3678.
  269. Highly Efficient and Selective Synthesis of Conjugated Triynes and Higher Oligoynes of Biological and Materials Chemical Interest via Palladium-Catalyzed Alkynyl–Alkenyl Coupling Métay, E.; Hu, Q.; Negishi, E. Org. Lett., 2006, 8, 5773-5776.
  270. ZACA Reaction: Zr-Catalyzed Asymmetric Carboalumination of Alkenes Negishi, E.; Liang, B.; Novak, T.; Tan, Z. Asymmetric Synthesis?The Essentials, Bräse, S.; Christmann, M., Eds., Wiley-VCH, Weinheim, 2007, 126-130.
  271. C–C Bond Formation (Part 1) by Addition Reactions: through Carbometallation Mediated by Group 4-7 Metals Negishi, E.; Novak, T. Comprehensive Organometallic Chemistry III, Vol. 10, Ojima, I., Ed., Elsevier, Oxford 2007, Chap. 10.06, 251-297.
  272. Transition Metal-Catalyzed Organometallic Reactions that Have Revolutionized Organic Synthesis (Vol. 80 Commemorative Accounts) Negishi, E. Bull. Chem. Soc. Jpn., 2007, 80, 233-257.
  273. Zirconium-Catalyzed Carboaluminumination of Alkenes: ZACA–Lipase-Catalyzed Acetylation Synergy Huang, Z.; Tan, Z.; Novak, T.; Zhu, G.; Negishi, E. Adv. Synth. Catal., 2007, 349, 539-545.
  274. Enantioselective Synthesis of (–)-Spongidepsin via the Zr-Catalyzed Asymmetric Carboalumination of Alkenes (ZACA Reaction) Zhu, G.; Negishi, E. Org. Lett., 2007, ASAP.
  275. Zirconicum-Catalyzed Methylalumination of Heterofunctional Arylethynes. Factors Affecing the Regio-, Stereo-, and Chemoselectivities Wang, G.; Zhu, G.; Negishi, E. J. Organomet. Chem., 2007, in press.
  276. Stereoselective Synthesis of Fully Hydroxy-Protected Mycolactones A and B and Their Stereoisomerization upon Deprotection Yin, N.; Wang, G.; Negishi, E. Angew. Chem. Int. Ed.

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